61039-29-0Relevant academic research and scientific papers
SYNTHESIS OF PIPERAZINOMYCIN, A NOVEL ANTIFUNGAL ANTIBIOTIC
Nishiyama, Shigeru,Nakamura, Kazuhiko,Suzuki, Yoshikazu,Yamamura, Shosuke
, p. 4481 - 4484 (2007/10/02)
Piperazinomycin, a novel antifungal antibiotic, has been synthesized from tetrabromotyrosyltyrosine, whose oxidation with thallium trinitrate (TTN) leads to the formation of a strained 14-membered ring similar to that of piperazinomycin as a key step.
ATTOGRAM-LEVEL DETECTION AND RELATIVE RESPONSE OF STRONG ELECTROPHORES BY GAS CHROMATOGRAPHY WITH ELECTRON CAPTURE DETECTION.
Corkill,Joppich,Kuttab,Giese
, p. 481 - 485 (2007/10/02)
The responses as peak areas of some divergent compounds, most of which are strong electron absorbers, are measured by gas chromatography with electron capture detection (GC-ECD). The most sensitive compounds are derivatized lodothyronines, which are essentially 20-fold more sensitive than lindane. N,N-Dipentafluorobenzoylpentafluoroaniline, a somewhat less sensitive but more volatile substance, was selected for determination of a detection limit. The value was 90 ag(1. 6 multiplied by 10** minus **1**9 mol), largely due to an anomalous increase in its response at the trace level. This increases the reported sensitivity of GC-ECD by 100-fold.
