6111-82-6

Basic information

• Product Name: [(E)-1-Hexenyl]benzene
• Synonyms: (E)-1-Phenyl-1-hexene;[(E)-1-Hexenyl]benzene
• CAS NO: 6111-82-6
• Molecular Formula: C₁₂H₁₆
• Molecular Weight: 160.26
• Mol File: 6111-82-6.mol
• Article Data: 145

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [(E)-1-Hexenyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [(E)-1-Hexenyl]benzene(6111-82-6)
• EPA Substance Registry System: [(E)-1-Hexenyl]benzene(6111-82-6)

Safety Data

• Hazardous Substances Data: 6111-82-6(Hazardous Substances Data)

Usage

General Description

[(E)-1-Hexenyl]benzene, also known as phenylhexene, is a chemical compound that consists of a hexenyl group attached to a benzene ring. It is a colorless liquid with a sweet, floral odor. [(E)-1-Hexenyl]benzene is commonly used as a flavoring agent in the food and beverage industry, providing a pleasant fragrance and taste to various products. It is also used in the production of perfumes and other cosmetics due to its aromatic properties. Additionally, [(E)-1-Hexenyl]benzene has applications in the pharmaceutical and chemical industries as an intermediate in the synthesis of other compounds. Overall, it is a versatile chemical with a range of industrial and commercial uses.

Upstream product

• 109-72-8 n-butyllithium 
• 622-25-3 1-(2-chlorovinyl)benzene 
• 103-64-0 bromostyrene 
• 21406-61-1 pentyltriphenylphosphonium bromide 
• 100-52-7 benzaldehyde 
• 88626-90-8 BuMnCl 
• 592-41-6 1-hexene 
• 108-86-1 bromobenzene 
• 591-50-4 iodobenzene 
• 88533-65-7 2-(Diphenyl-phosphinoyl)-1-phenyl-hexan-1-ol 
• 88533-65-7 threo-2-diphenylphosphinoyl-1-phenylhexan-1-ol 
• 88533-65-7 erythro-2-diphenylphosphinoyl-1-phenylhexan-1-ol 
• 85260-47-5 cis-2-(1'-butyl)-1-(trimethylsilyl)oxirane 
• 591-51-5 phenyllithium 

Downstream Products

• 1536240-42-2 (1-phenylhexan-2-yl)phosphinic acid 
• 123-01-3 1-dodecylbenzene 
• 14371-10-9 (E)-3-phenylpropenal 
• 82297-62-9 (E)-1-phenylhex-1-en-3-one 
• 100-52-7 benzaldehyde 
• 65-85-0 benzoic acid 
• 1674-38-0 dodecanophenone 
• 198956-51-3 (3S)-2-Benzylheptane 
• 4471-05-0 (R)-1-phenyl-1-hexanol 

Relevant articles and documents

Ir-Catalyzed Remote Functionalization by the Combination of Deconjugative Chain-Walking and C-H Activation Using a Transient Directing Group

An Ir-catalyzed reaction of N-benzylideneanilines with functionalized alkenes such as α,β-unsaturated esters gave ortho-substituted benzaldehyde derivatives with a functional group at the remote position after acidic treatment. The present transformation

Selective hydroboration of equilibrating allylic azides

The iridium(i)-catalyzed hydroboration of equilibrating allylic azides is reported to provide only the anti-Markovnikov product of alk-1-ene isomers in good yields and with good functional group tolerance.

Dinuclear cobalt complex-catalyzed stereodivergent semireduction of alkynes: Switchable selectivities controlled by H2O

Catalytic semireduction of internal alkynes to alkenes is very important for organic synthesis. Although great success has been achieved in this area, switchable Z/E stereoselectivity based on a single catalyst for the semireduction of internal alkynes is a longstanding challenge due to the multichemo- and stereoselectivity, especially based on less-expensive earth-abundant metals. Herein, we describe a switchable semireduction of alkynes to (Z)- or (E)-alkenes catalyzed by a dinuclear cobalt complex supported by a macrocyclic bis pyridyl diimine (PDI) ligand. It was found that cis-reduction of the alkyne occurs first and the Z-E alkene stereoisomerization process is formally controlled by the amount of H2O, since the concentration of H2O may influence the catalytic activity of the catalyst for isomerization. Therefore, this protocol provides a facile way to switch to either the (Z)- or (E)-olefin isomer in a single transformation by adjusting the amount of water.