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6120-96-3

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6120-96-3 Usage

General Description

Cyclopropanecarboxamide, 1-phenyl- is a chemical compound with the molecular formula C9H9NO. It is a member of the cyclopropane carboxamide family and is also known by its systematic name, 1-phenylcyclopropanecarboxamide. Cyclopropanecarboxamide, 1-phenyl- (7CI,8CI,9CI) is commonly used in organic synthesis and pharmaceutical research as a building block for the development of new drugs and agrochemicals. It is also used as a reagent in chemical reactions to introduce the cyclopropyl group into organic molecules. Its properties and reactivity make it a versatile and important compound in the field of organic chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 6120-96-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,1,2 and 0 respectively; the second part has 2 digits, 9 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 6120-96:
(6*6)+(5*1)+(4*2)+(3*0)+(2*9)+(1*6)=73
73 % 10 = 3
So 6120-96-3 is a valid CAS Registry Number.
InChI:InChI=1/C10H11NO/c11-9(12)10(6-7-10)8-4-2-1-3-5-8/h1-5H,6-7H2,(H2,11,12)

6120-96-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-phenylcyclopropane-1-carboxamide

1.2 Other means of identification

Product number -
Other names 1-phenylcyclopropanecarboxamide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6120-96-3 SDS

6120-96-3Relevant articles and documents

Cloke,Knowles,Anderson

, p. 2547 (1936)

Bromomethyl Silicate: A Robust Methylene Transfer Reagent for Radical-Polar Crossover Cyclopropanation of Alkenes

Luo, Wenping,Fang, Yewen,Zhang, Li,Xu, Tianhang,Liu, Yongjun,Li, Yan,Jin, Xiaoping,Bao, Jiakan,Wu, Xiaodong,Zhang, Zongyong

supporting information, p. 1778 - 1781 (2020/03/11)

A general protocol for visible-light-induced cyclopropanation of alkenes was developed with bromomethyl silicate as a methylene transfer reagent, offering a robust tool for accessing highly valuable cyclopropanes. In addition to α-aryl or methyl-substituted Michael acceptors and styrene derivatives, the unactivated 1,1-dialkyl ethylenes were also shown to be viable substrates. Apart from realizing the cyclopropanation of terminal alkenes, the methyl transfer reaction has been further demonstrated to be amenable to the internal olefins. The photocatalytic cyclopropanation of 1,3-bis(1-arylethenyl)benzenes was also achieved, giving polycyclopropane derivatives in excellent yields. With late-stage cyclopropanation as the key strategy, the synthetic utility of this transformation was also demonstrated by the total synthesis of LG100268.

Visible-Light-Promoted Redox-Neutral Cyclopropanation Reactions of α-Substituted Vinylphosphonates and Other Michael Acceptors with Chloromethyl Silicate as Methylene Transfer Reagent

Guo, Ting,Zhang, Li,Liu, Xiaobo,Fang, Yewen,Jin, Xiaoping,Yang, Yi,Li, Yan,Chen, Bin,Ouyang, Minghui

supporting information, p. 4459 - 4463 (2018/09/14)

The alkene cyclopropanation with chloromethyl silicate as a methylene transfer reagent has been accomplished via visible-light-mediated redox-neutral catalysis. This method features broad functional group tolerance and mild conditions. In addition to α-substituted vinylphosphonates, a range of Michael acceptors including α,β-unsaturated acrylate, ketone, amide and sulfone are suitable substrates for this photocatalytic cyclopropanation. An application of this protocol to the cyclopropanation of estrone derivative is also presented. (Figure presented.).

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