613-56-9

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 45, p. 3840, 1980 DOI: 10.1021/jo01307a022

InChI:InChI=1/C21H14O/c22-21(19-11-9-15-5-1-3-7-17(15)13-19)20-12-10-16-6-2-4-8-18(16)14-20/h1-14H

Upstream product

• 21473-01-8 2-naphthalenylmagnesium bromide 
• 2243-83-6 2-naphthaloyl chloride 
• 19226-36-9 3-phenyl-5H-1,4,2-dioxazol-5-one 
• 4541-70-2 2-naphthyllithium 

Downstream Products

• 216070-60-9 tri(naphthalene-2-yl)methanol 
• 225367-72-6 C₂₈H₂₂N₂O₂S 
• 91-20-3 naphthalene 
• 93-09-4 naphthalene-2-carboxylate 
• 1426339-73-2 tri(naphthalen-2-yl)phenylethene 
• 4809-95-4 bis(β-naphthyl)methanol 
• 76385-35-8 (2-allylphenyl)(phenyl)methanone 
• 612-78-2 2,2'-binaphthalene 

Relevant academic research and scientific papers

Co(III)-Catalyzed Synthesis of Quinazolines via C-H Activation of N-Sulfinylimines and Benzimidates

C-H activation of arenes has been established as an important strategy for heterocycle synthesis via annulations between arenes and unsaturated coupling partners. However, nitriles failed to act as such a coupling partner. Dioxazolones have been employed as a synthon of nitriles, and subsequent coupling with arenes such as N-sulfinylimines and benzimidates bearing a functionalizable directing group provided facile access to two classes of quinazolines under Co(III)-catalysis.

Difluoroboroxymolybdenum fischer carbene complexes as precursors of acyl radicals: Dimerization and trapping with electron-deficient alkenes

Pentacarbonyl acyl molybdates 1 react with boron trifluoride to give difluoroboroxy Fischer carbene complexes 2, which undergo loss of the metal fragment at room temperature to form 1,2-diketones 3, 1,2-hydroxy ketones 4, or dimers 5 through a dimerization or decarbonylation-dimerization process of acyl radicals. Decomposition of 2 in the presence of electron-deficient alkenes 11 and 18 furnishes the two-, three-, and four-component coupling products 12, 13, 19, 20, and 21.