6136-66-9

Basic information

• Product Name: 4-IODOBENZOPHENONE
• Synonyms: 4-IODOBENZOPHENONE
• CAS NO: 6136-66-9
• Molecular Formula: C₁₃H₉IO
• Molecular Weight: 308.11
• Mol File: 6136-66-9.mol
• Article Data: 31

Chemical Properties

• Melting Point: 97-99°C
• Boiling Point: 366.6 °C at 760 mmHg
• Flash Point: 175.5 °C
• Appearance: /
• Density: 1.624 g/cm³
• Vapor Pressure: 1.45E-05mmHg at 25°C
• Refractive Index: 1.647
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• CAS DataBase Reference: 4-IODOBENZOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-IODOBENZOPHENONE(6136-66-9)
• EPA Substance Registry System: 4-IODOBENZOPHENONE(6136-66-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• HazardClass: IRRITANT
• Hazardous Substances Data: 6136-66-9(Hazardous Substances Data)

Usage

Description

4-Iodobenzophenone, with the molecular formula C13H9IO, is a pale yellow solid chemical compound that is soluble in organic solvents. It serves as a versatile building block in the synthesis of various organic compounds and is known for its potential environmental hazard due to its toxic and irritant properties, necessitating careful handling and appropriate safety precautions.

Uses

Used in Pharmaceutical Industry:
4-Iodobenzophenone is used as a key intermediate in the synthesis of pharmaceuticals for its ability to contribute to the development of new drugs and medicinal compounds.
Used in Dye Industry:
In the dye industry, 4-Iodobenzophenone is utilized as a precursor in the production of dyes, contributing to the creation of a wide range of colorants for various applications.
Used in Organic Chemicals Production:
4-Iodobenzophenone is employed as a building block in the synthesis of other organic chemicals, playing a crucial role in the development of diverse chemical products.
Used in UV-Curable Inks and Coatings:
4-Iodobenzophenone is used as a photoinitiator in the formulation of UV-curable inks and coatings, enabling rapid curing under ultraviolet light and improving the efficiency of the curing process.

InChI:InChI=1/C13H9IO/c14-12-8-6-11(7-9-12)13(15)10-4-2-1-3-5-10/h1-9H

Upstream product

• 15164-44-0 p-(iodophenyl)carboxaldehyde 
• 63468-90-6 phenylglyoxylic acid potassium salt 
• 591-50-4 iodobenzene 
• 98-88-4 benzoyl chloride 
• 106480-53-9 4-dichloroiodanyl-benzophenone 
• 172483-72-6 4-iodobenzhydrol 
• 94089-31-3 1-iodo-4-(1-phenylvinyl)benzene 
• 3956-07-8 4-iodobenzamide 
• 619-58-9 4-iodobenzoic acid 
• 201230-82-2 carbon monoxide 
• 624-38-4 para-diiodobenzene 
• 143-66-8 sodium tetraphenyl borate 
• 98-80-6 phenylboronic acid 
• 3058-39-7 4-iodobenzonitrile 

Downstream Products

• 611-95-0 4-carboxybenzophenone 
• 165898-66-8 4-(4-tert-butylphenoxy)benzophenone 
• 41830-99-3 phenyl({4-[(trifluoromethyl)sulfanyl]phenyl})methanone 
• 1503-49-7 p-cyanobenzophenone 
• 1393479-20-3 phenyl(4-(2,2,2-trifluoroethyl)phenyl)methanone 
• 119-61-9 benzophenone 
• 2128-93-0 biphenyl-4-yl-phenyl-methanone 
• 115216-92-7 (4-[¹⁸F]fluorophenyl)(phenyl)methanone 
• 1453864-77-1 [4-(phenylcarbonyl)phenyl](4’-methoxyphenyl)iodonium tosylate 
• 64747-73-5 4-[(difluoromethyl)phenyl](phenyl)methanone 
• 345-83-5 4-fluorobenzophenone 
• 1137-42-4 4-Hydroxybenzophenone 
• 1137-41-3 (4-aminophenyl)(phenyl)methanone 
• 931607-27-1 4-benzoyl-N-methylbenzamide 

Relevant articles and documents

Photo-induced oxidative cleavage of C-C double bonds of olefins in water

The carbonyl compounds, synthesized by the oxidative cleavage of their corresponding olefins, are of great significance in organic synthesis, especially aryl ketones. We have developed a gentle and effective protocol, using acid red 94 as the organic metal-free photocatalyst, O2 as the oxidant, and water as the solvent. Under visible light irradiation, aryl ketone derivatives were obtained in moderate to excellent yields, showing good economic and environmental advantages.

Aryl aldiketone and synthesis method thereof

The invention discloses an aryl aldehyde ketone and a synthesis method thereof, wherein an aryl aldehyde is synthesized from cheap olefin as a raw material. A commercially available inexpensive olefin is used as a raw material, ether is used as an additive, molecular oxygen serves as a sole oxidizing agent, water is used as a solvent, and the aldehyde and ketone are synthesized by column chromatography under a photocatalytic condition. The invention has the advantages of mild reaction conditions, green and environmental protection, simple experimental operation, good reaction selectivity, high product yield and the like.

Hydrogen-Bond-Donor Solvents Enable Catalyst-Free (Radio)-Halogenation and Deuteration of Organoborons

A hydrogen bond donor solvent assisted (radio)halogenation and deuteration of organoborons has been developed. The reactions exhibited high functional group tolerance and needed only an ambient atmosphere. Most importantly, compared to literature methods, our conditions are more consistent with the principals of green chemistry (e.g., metal-free, strong oxidant-free, more straightforward conditions).