94089-31-3Relevant articles and documents
Arylation of Olefins by N-Nitroso-N-arylacetamides under Palladium(0) Catalysis: A New Precursor of Arylpalladium Species
Kikukawa, Kiyoshi,Naritomi, Masaki,He, Gong-Xin,Wada, Fumio,Matsuda, Tsutomu
, p. 299 - 301 (1985)
Olefins (styrene, octene-1, cycloheptene, ethyl acrylate, and vinyl acetate) were easily arylated in good yields with N-nitroso-N-arylacetamides (ArN(NO)COCH3: Ar= Ph, 4-MeC6H4, 4-MeOC6H4, 4-ClC6H4, 4-BrC6H4, and 4-IC6H4) under palladium(0) catalysis at 40 deg C within 40 min.
Efficient synthesis of polysubstituted olefins using stable palladium nanocatalyst: Applications in synthesis of tamoxifen and isocombretastatin A4
Ganapathy, Dhandapani,Sekar, Govindasamy
supporting information, p. 3856 - 3859 (2014/08/18)
A phosphine-free stable palladium nanocatalyst was used for an efficient synthesis of polysubstituted olefins from N-tosylhydrazones and aryl iodides. This methodology was successfully utilized in the synthesis of biologically important tamoxifen and isocombretastatin A4. The nanocatalyst was easily recovered and reused without any apparent loss in size and catalytic activity.