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614-21-1 Usage


Benzoylnitromethane is a white waxy crystalline powder or flake, which is known for its unique chemical properties and potential applications in various fields.


Used in Chemical Research:
Benzoylnitromethane is used as a research compound for studying the kinetics of proton transfer to various bases. This helps in understanding the fundamental chemical reactions and interactions that occur in different chemical systems.
Used in Pharmaceutical Industry:
Benzoylnitromethane is used as an intermediate in the synthesis of pharmaceutical compounds. Its unique chemical properties make it a valuable component in the development of new drugs and medications.
Used in Organic Synthesis:
Benzoylnitromethane is used as a reagent in organic synthesis, particularly in the preparation of various organic compounds. Its ability to transfer protons makes it a useful tool in the synthesis of complex organic molecules.
Used in Analytical Chemistry:
Benzoylnitromethane is used as an analytical reagent in various analytical techniques, such as spectrophotometry and chromatography. Its unique properties allow for the accurate determination of different chemical compounds and their concentrations.

Check Digit Verification of cas no

The CAS Registry Mumber 614-21-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 6,1 and 4 respectively; the second part has 2 digits, 2 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 614-21:
51 % 10 = 1
So 614-21-1 is a valid CAS Registry Number.



According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017


1.1 GHS Product identifier

Product name Benzoylnitromethane

1.2 Other means of identification

Product number -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:614-21-1 SDS

614-21-1Relevant articles and documents

Nickel-Catalyzed Reductive Cross-Coupling of N-Acyl and N-Sulfonyl Benzotriazoles with Diverse Nitro Compounds: Rapid Access to Amides and Sulfonamides

Qu, Erdong,Li, Shangzhang,Bai, Jin,Zheng, Yan,Li, Wanfang

supporting information, p. 58 - 63 (2021/12/27)

Herein we report a Ni-catalyzed reductive transamidation of conveniently available N-acyl benzotriazoles with alkyl, alkenyl, and aryl nitro compounds, which afforded various amides with good yields and a broad substrate scope. The same catalytic reaction conditions were also applicable for N-sulfonyl benzotriazoles, which could undergo smooth reductive coupling with nitroarenes and nitroalkanes to afford the corresponding sulfonamides.

Synthesis of 3-nitroindoles by sequential paired electrolysis

Kilmartin, Paul A.,Lindsay, Ashley C.,Sperry, Jonathan

supporting information, p. 7903 - 7913 (2021/09/28)

3-Nitroindoles are synthetically versatile intermediates but current methods for the preparation hinder their widespread application. Herein, we report that nitroenamines undergo electrochemical cyclisation to 3-nitroindoles in the presence of potassium iodide. Detailed control experiments and cyclic voltammogram studies infer the reaction proceedsviaa sequential paired electrolysis process, beginning with anodic oxidation of iodide (I?) to the iodine radical (I˙), which facilitates cyclisation of the nitroenamine to give a 3-nitroindolinyl radical. Cathodic reduction and protonation generates a 3-nitroindoline that upon oxidation forms the 3-nitroindole.

Ionic-Liquid Controlled Nitration of Double Bond: Highly Selective Synthesis of Nitrostyrenes and Benzonitriles

Casiello, Michele,Caputo, Daniela,Fusco, Caterina,Cotugno, Pietro,Rizzi, Vito,Dell'Anna, Maria Michela,D'Accolti, Lucia,Nacci, Angelo

supporting information, p. 6012 - 6018 (2020/08/24)

Unprecedented in literature, the conversion of aryl alkenes into β-nitrostyrenes (2) or benzonitriles (3) with sodium nitrite can be governed by an appropriate choice of ionic liquid (IL) medium. A general trend was found for the selectivity of these processes, which depends on the nature of IL, with imidazolium-based ILs, such as [Bmim]Cl, that favor the C–H nitration leading to β-nitrostyrenes, while tetraalkylammonium-based ILs, such as TBAA, privilege the C=C bond cleavage affording benzonitriles. Besides a substrate scope, mechanistic hypotheses were provided on the origin of the different selectivity in the two kinds of ILs, based on their own tunable properties such as polarity, viscosity, and solvent cage effects.

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