6143-30-2Relevant articles and documents
Epoxidation and oxidative dihydroxylation of C10–C13 unsaturated bridged hydrocarbons involving hydrogen peroxide and modified forms of heteromolybdic compounds
Alimardanov, Kh. M.,Sadygov,Garibov,Dadashova,Almardanova,Kuliev
, p. 415 - 423 (2017/07/05)
Induced oxidation of C10–C13 tricyclic bridged olefins synthesized from C5–C8 cyclodiene hydrocarbons using hydrogen peroxide has been studied. It has been shown that phosphomolybdic heteropoly compounds supported on a finely divided carbon material and additionally modified with HBr and CoCO3 or Gd2O3 exhibit high activity in this reaction. Depending on the conditions of the experiments, the main reaction products are the corresponding oxiranes and diols that retain the structure of the reactant hydrocarbons.
[2+4] Cycloaddition of η6-(styrene)chromium tricarbonyl and conjugated dienes
Artemov,Sazonova,Revin,Rybkin,Lazarev,Faerman
experimental part, p. 2103 - 2106 (2012/09/22)
Cycloaddition of η6-(styrene)chromium tricarbonyl to hexa-2,4-diene or cyclopentadiene afford the Diels-Alder adducts with retention of the Cr(CO)3 group, whereas cyclohexa-1,3-diene undergoes aromatization to give η6-(ben
A highly efficient palladacycle catalyst for hydrophenylation of C-, N-, and O-substituted bicyclic alkenes under aerobic condition
Yuan, Ke,Zhang, Ting Ke,Hou, Xue Long
, p. 6085 - 6088 (2007/10/03)
A new phosphine-free palladacycle catalyst 4 was prepared from benzyl oxazoline in high yield and fully characterized. With it as catalyst, hydrophenylation reactions of a wide range of bicyclic alkenes, not only norbomene and norborriadiene but also oxa-