6143-30-2

Usage

Uses

Used in Materials Science:
5-NORBORNENE-2-PHENYL is used as a monomer in the production of polymers and resins for various applications due to its unique chemical structure and properties that contribute to the desired characteristics of the final products.
Used in Pharmaceutical Industry:
5-NORBORNENE-2-PHENYL is used as a building block in organic synthesis for the development of pharmaceuticals, leveraging its chemical properties to create new and effective drug molecules.
Used in Agrochemical Development:
5-NORBORNENE-2-PHENYL is utilized as a key intermediate in the synthesis of agrochemicals, contributing to the creation of innovative products for agricultural applications.
Used in Industrial Chemistry:
5-NORBORNENE-2-PHENYL is employed as a specialty chemical in various industrial processes, taking advantage of its unique properties to enhance the performance of different chemical formulations and products.

InChI:InChI=1/C13H14/c1-2-4-11(5-3-1)13-9-10-6-7-12(13)8-10/h1-7,10,12-13H,8-9H2

Upstream product

• 100-42-5 styrene 
• 1755-01-7 endo-Dicyclopentadien 
• 542-92-7 cyclopenta-1,3-diene 
• 141831-92-7 C₃₃H₂₄O₄S₂ 
• 77-73-6 bi(cyclopentadiene) 
• 498-66-8 norborn-2-ene 
• 71-43-2 benzene 
• 591-50-4 iodobenzene 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 141832-07-7 2-benzylidene-dinaphtho<2,1-d:1',2'-f><1,3>dithiepine-S,S'-tetroxide 
• 141831-77-8 2-benzylidene-dinaphtho<2,1-d:1',2'-f><1,3>dithiepine 

Downstream Products

• 71173-15-4 acetic acid-(1-phenyl-[2]norbornyl ester) 
• 92251-47-3 formic acid-(1-phenyl-[2]norbornyl ester) 
• 42114-05-6 methyl-(1-phenyl-[2]norbornyl)-ether 
• 17989-94-5 endo-2-phenylbicyclo<2.2.1>heptane 

Relevant academic research and scientific papers

Epoxidation and oxidative dihydroxylation of C10–C13 unsaturated bridged hydrocarbons involving hydrogen peroxide and modified forms of heteromolybdic compounds

Induced oxidation of C10–C13 tricyclic bridged olefins synthesized from C5–C8 cyclodiene hydrocarbons using hydrogen peroxide has been studied. It has been shown that phosphomolybdic heteropoly compounds supported on a finely divided carbon material and additionally modified with HBr and CoCO3 or Gd2O3 exhibit high activity in this reaction. Depending on the conditions of the experiments, the main reaction products are the corresponding oxiranes and diols that retain the structure of the reactant hydrocarbons.

[2+4] Cycloaddition of η6-(styrene)chromium tricarbonyl and conjugated dienes

Cycloaddition of η6-(styrene)chromium tricarbonyl to hexa-2,4-diene or cyclopentadiene afford the Diels-Alder adducts with retention of the Cr(CO)3 group, whereas cyclohexa-1,3-diene undergoes aromatization to give η6-(ben

Microwave-assisted solvent-free Diels-Alder reaction - A fast and simple route to various 5,6-substituted norbornenes and polychlorinated norbornenes

A series of 5,6-substituted norbornenes and 5,6-substituted polychlorinated norbornenes was prepared by using a microwave-assisted Diels-Alder reaction. This procedure proved very versatile, fast, and with an easy workup step, and therefore suitable even for large-scale synthesis. Georg Thieme Verlag Stuttgart · New York.

New phosphine-functionalized N-heterocyclic carbene ligands for palladium-catalyzed hydroarylation reaction

Novel triarylphosphine-functionalized imidazolinium salts have been prepared and successfully applied in palladium-catalyzed hydroarylation of bicyclic olefins. Under reductive conditions (HCOOH, Et3N), the complexes generated in situ from imidazolinium salts and Pd(OAc)2 catalyzed the hydroarylation of bicyclic alkenes with aryl iodides, providing the hydroarylation products with high turnover numbers (TON, up to 1.9-10 5) and turnover frequencies (TOF, up to 6.3-104). Georg Thieme Verlag Stuttgart.

A highly efficient palladacycle catalyst for hydrophenylation of C-, N-, and O-substituted bicyclic alkenes under aerobic condition

A new phosphine-free palladacycle catalyst 4 was prepared from benzyl oxazoline in high yield and fully characterized. With it as catalyst, hydrophenylation reactions of a wide range of bicyclic alkenes, not only norbomene and norborriadiene but also oxa-

Esters Synthesis by Addition of Monocarboxylic Acids to exo-5-Substituted Bicyclo[2.2.1]hept-2-ene Hydrocarbons

New alicyclic esters were synthesized by addition at heating of aliphatic monocarboxylic saturated acids C1-C4 to exo-5-phenyl-, exo-5-cyclohexyl-, and exo-5-(cyclohex-3-enyl)bicyclo[2.2.1]hept-2-enes. Among the esters obtained the acetates has more pleasant odor with fruit tint, and they may be used as a comp onent of synthetic perfumes.

Nickel catalysts for polymerization

A method for the polymerization of cycloolefins in a presence of a nickel (0) compound or a compound which can be converted in situ into a nickel (0) compound, as a catalyst. The catalyst of the present invention exhibits very high catalytic activity towards polymerization of cycloolefins.

Scandium(III) triflate immobilised in ionic liquids: a novel and recyclable catalytic system for Friedel-Crafts alkylation of aromatic compounds with alkenes

Scandium(III) triflate catalysed Friedel-Crafts alkylation of aromatic compounds with alkenes proceeded readily in the hydrophobic ionic liquid solvents based on 1,3-dialkylimidazolium salts with easy catalyst/solvent recycling, whereas these reactions did not occur in common organic solvents, water or hydrophilic ionic liquids at all.

Highly efficient phosphapalladacyclic catalysts for the hydroarylation of norbornene

Exceptionally high turnover numbers of up to 196 x 106 moles of product per mole of catalyst, turnover frequencies of up to 12 x 106 moles of product per mole of catalyst per hour, and yields of 98% were achieved in the hydroarylatio

Process for isomerizing endo-form of aromatic group-containing norbornenes to exo-form thereof, isomer mixture of aromatic group-containing norbornenes and process for preparing same, and ethylene/aromatic group-containing norborne copolymer and process

A process for isomerization of an endo-form of aromatic group-containing norbornenes represented by the following formula (I) to an exo-form which comprises bringing the endo-form into contact with a solid acid catalyst. STR1 wherein p is 0 or an integer of 1 or more, q and r are each 0, 1 or 2, R1 to R15 are each independently hydrogen or halogen atom, aliphatic hydrocarbon group, aromatic hydrocarbon group or alkoxy group, R5 (or R6) are R9 (or R7) may be linked together through an alkylene group of 1-3 carbons or may be directly linked together.