61593-04-2

Basic information

• Product Name: Benzenemethanol, 2-bromo-a-(1,1-dimethylethyl)-
• CAS NO: 61593-04-2
• Molecular Formula: C11H15BrO
• Molecular Weight: 243.143
• Mol File: 61593-04-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 297.7±15.0 °C(Predicted)
• Density: 1.305±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzenemethanol, 2-bromo-a-(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-bromo-a-(1,1-dimethylethyl)-(61593-04-2)
• EPA Substance Registry System: Benzenemethanol, 2-bromo-a-(1,1-dimethylethyl)-(61593-04-2)

Safety Data

• Hazardous Substances Data: 61593-04-2(Hazardous Substances Data)

Upstream product

• 507-20-0 tertiary butyl chloride 
• 6630-33-7 ortho-bromobenzaldehyde 
• 7154-66-7 2-bromobenzoic acid chloride 
• 61593-14-4 1-(2-bromophenyl)-2,2-dimethyl-propan-1-one 
• 2259-30-5 tert-butylmagnesium bromide 
• 18982-54-2 o-bromobenzyl alcohol 
• 594-19-4 tert.-butyl lithium 

Downstream Products

• 61593-14-4 1-(2-bromophenyl)-2,2-dimethyl-propan-1-one 
• 61592-96-9 C₁₇H₁₉Cl₂P 
• 61592-97-0 C₁₇H₁₉AsCl₂ 
• 61592-94-7 1-Bromo-2-(1,2-dimethyl-2-phenyl-propyl)-benzene 
• 61592-95-8 1-Bromo-2-(1,1-dimethyl-2-phenyl-propyl)-benzene 
• 61593-15-5 1-(2-Bromphenyl)-1-phenyl-2,2-dimethylpropan 
• 23450-18-2 2-benzyl-1-bromobenzene 
• 61593-05-3 1-(2-Bromo-phenyl)-2,2-dimethyl-1-phenyl-propan-1-ol 
• 500898-93-1 (RS,RS)-Bis[2-(2,2-dimethyl-1-hydroxypropyl)phenyl] diselenide 

Relevant articles and documents

The intramolecular reaction of acetophenoneN-tosylhydrazone and vinyl: Br?nsted acid-promoted cationic cyclization toward polysubstituted indenes

In the presence of TsNHNH2, a Br?nsted acid-promoted intramolecular cyclization ofo-(1-arylvinyl) acetophenone derivatives was developed, leading to polysubstituted indenes with complexity and diversity in moderate to excellent yields. In sharp contrast with either the radical or carbene involved cyclization of aldehydicN-tosylhydrazone with vinyl, a cationic cyclization pathway was involved, whereN-tosylhydrazone served as an electrophile and alkylation reagent during this transformation.

Diisobutylaluminum hydride-promoted cyclization of benzyl and phenylsilyl ethers bearing a 2-(trimethylsilyl)ethynyl group: syntheses of indenes and benzosiloles

The reaction of o-[2-(trimethylsilyl)ethynyl]benzyl methyl ethers with diisobutylaluminum hydride (DIBAL-H) gave 2-(trimethylsilyl)indenes in good yields. This cyclization proceeds by regio- and stereoselective hydroalumination of the alkyne moiety followed by intramolecular nucleophilic substitution. o-[2-(Trimethylsilyl)ethynyl]phenylsilyl methyl ethers also underwent the DIBAL-H promoted-cyclization to be converted into 2-(trimethylsilyl)benzosiloles in good yields. This approach provides straightforward and efficient way to construct benzosiloles from readily available organosilanes.