61593-14-4

Basic information

• Product Name: 1-Propanone, 1-(2-bromophenyl)-2,2-dimethyl-
• Synonyms: tert.-Butyl-o-bromphenylketon
• CAS NO: 61593-14-4
• Molecular Formula: C11H13BrO
• Molecular Weight: 241.128
• Mol File: 61593-14-4.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 1-(2-bromophenyl)-2,2-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 1-(2-bromophenyl)-2,2-dimethyl-(61593-14-4)
• EPA Substance Registry System: 1-Propanone, 1-(2-bromophenyl)-2,2-dimethyl-(61593-14-4)

Safety Data

• Hazardous Substances Data: 61593-14-4(Hazardous Substances Data)

Upstream product

• 2142-69-0 2-bromophenyl methyl ketone 
• 74-88-4 methyl iodide 
• 18982-54-2 o-bromobenzyl alcohol 
• 677-22-5 tert-butylmagnesium chloride 
• 7154-66-7 2-bromobenzoic acid chloride 
• 938-16-9 2,2-dimethylpropiophenone 
• 6630-33-7 ortho-bromobenzaldehyde 
• 88-65-3 2-bromobenzoic-acid 
• 2259-30-5 tert-butylmagnesium bromide 
• 108-86-1 bromobenzene 
• 3282-30-2 pivaloyl chloride 
• 61593-04-2 (±)-1-(2'-bromophenyl)-2,2-dimethyl-1-propanol 

Downstream Products

• 10489-28-8 2,2-dimethyl-indan-1-one 
• 61593-04-2 (±)-1-(2'-bromophenyl)-2,2-dimethyl-1-propanol 
• 61592-96-9 C₁₇H₁₉Cl₂P 
• 61592-97-0 C₁₇H₁₉AsCl₂ 
• 61592-94-7 1-Bromo-2-(1,2-dimethyl-2-phenyl-propyl)-benzene 
• 61592-95-8 1-Bromo-2-(1,1-dimethyl-2-phenyl-propyl)-benzene 
• 61593-15-5 1-(2-Bromphenyl)-1-phenyl-2,2-dimethylpropan 
• 23450-18-2 2-benzyl-1-bromobenzene 
• 61593-05-3 1-(2-Bromo-phenyl)-2,2-dimethyl-1-phenyl-propan-1-ol 

Relevant articles and documents

The intramolecular reaction of acetophenoneN-tosylhydrazone and vinyl: Br?nsted acid-promoted cationic cyclization toward polysubstituted indenes

In the presence of TsNHNH2, a Br?nsted acid-promoted intramolecular cyclization ofo-(1-arylvinyl) acetophenone derivatives was developed, leading to polysubstituted indenes with complexity and diversity in moderate to excellent yields. In sharp contrast with either the radical or carbene involved cyclization of aldehydicN-tosylhydrazone with vinyl, a cationic cyclization pathway was involved, whereN-tosylhydrazone served as an electrophile and alkylation reagent during this transformation.

High-yielding, versatile, and practical [Rh(III)Cp*]-catalyzed ortho bromination and iodination of arenes

We report a uniquely high-yielding, general, and practical ortho bromination and iodination reaction of different classes of aromatic compounds. This reaction occurs by Rh(III)-catalyzed C-H bond activation methodology and is therefore the first example of the application of this cationic catalyst for C-Br and C-I bond formation.

Unexpected cross-coupling reaction between o-chloroaryl ketones and organomanganese reagents

(Chemical equation presented) Alkyl- and arylmanganese reagents react with o-chloro or o-bromoaryl ketones to give the substituted ketones in high yields. The cross-coupling reaction is performed under mild conditions (-60 to +40°C, 30 min to 4 h) and tak