616873-78-0

Basic information

• Product Name: Acetic acid, 2,2'-[1,4-phenylenebis(oxy)]bis-, bis[3-(1,1-dimethylethyl)-5-formyl-4-hydroxyphenyl] ester
• CAS NO: 616873-78-0
• Molecular Formula: C32H34O10
• Molecular Weight: 578.616
• Mol File: 616873-78-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetic acid, 2,2'-[1,4-phenylenebis(oxy)]bis-, bis[3-(1,1-dimethylethyl)-5-formyl-4-hydroxyphenyl] ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, 2,2'-[1,4-phenylenebis(oxy)]bis-, bis[3-(1,1-dimethylethyl)-5-formyl-4-hydroxyphenyl] ester(616873-78-0)
• EPA Substance Registry System: Acetic acid, 2,2'-[1,4-phenylenebis(oxy)]bis-, bis[3-(1,1-dimethylethyl)-5-formyl-4-hydroxyphenyl] ester(616873-78-0)

Safety Data

• Hazardous Substances Data: 616873-78-0(Hazardous Substances Data)

Upstream product

• 2245-53-6 2,2'-[1,4-phenylenebis(oxy)]bisacetic acid 
• 192803-37-5 3-tert-butyl-2,5-dihydroxybenzaldehyde 
• 5897-78-9 (4-ethoxycarbonylmethoxy-phenoxy)-acetic acid ethyl ester 
• 3421-95-2 4-(benzyloxy)-2-(tert-butyl)phenol 
• 123-31-9 hydroquinone 
• 1948-33-0 tert-butylhydroquinone 
• 192803-36-4 5-benzyloxy-3-tert-butyl-2-hydroxy-benzaldehyde 

Relevant articles and documents

Polymeric salen-Ti(IV) or V(V) complex catalyzed asymmetric synthesis of O-acetylcyanohydrins from KCN, Ac2O and aldehydes

Polymeric salen-Ti(IV) and V(V) complexes were employed in the enantioselective O-acetyl cyanation of aldehydes with potassium cyanide and acetic anhydride. The crosslinked polymeric salen-Ti(IV) catalyst exhibited good activities and enantioselectivities, up to 91% ee with 99% conversion was obtained at -20°C with 1 mol% of catalyst (based on bimetallic catalytic unit). Moreover, six consecutive recyclings with the easily recovered crosslinked polymeric catalyst showed no obvious decrease in either activity or enantioselectivity. Linear polymeric salen-V(V) catalyst showed good catalytic efficiency too, up to 94% ee with 99% conversion was obtained at -42°C with 5 mol% of catalyst. Graphical Abstract.