81470-75-9

Basic information

• Product Name: (Z)-(R)-5-Benzyloxy-4-methyl-pent-2-enoic acid methyl ester
• Synonyms: (Z)-(R)-5-Benzyloxy-4-methyl-pent-2-enoic acid methyl ester
• CAS NO: 81470-75-9
• Molecular Weight: 234.295
• Mol File: 81470-75-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-(R)-5-Benzyloxy-4-methyl-pent-2-enoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-(R)-5-Benzyloxy-4-methyl-pent-2-enoic acid methyl ester(81470-75-9)
• EPA Substance Registry System: (Z)-(R)-5-Benzyloxy-4-methyl-pent-2-enoic acid methyl ester(81470-75-9)

Safety Data

• Hazardous Substances Data: 81470-75-9(Hazardous Substances Data)

Upstream product

• 81520-06-1 ((R)-4,4-Dibromo-2-methyl-but-3-enyloxymethyl)-benzene 
• 81470-71-5 ((S)-3-tert-Butoxy-2-methyl-propoxymethyl)-benzene 
• 100-39-0 benzyl bromide 
• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 63930-49-4 (R)-3-(benzyloxy)-2-methylpropan-1-ol 
• 81470-74-8 (R)-5-Benzyloxy-4-methyl-pent-2-ynoic acid methyl ester 

Downstream Products

• 73814-75-2 [(2S,3S)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-oxiranyl]-methanol 
• 73814-75-2 [(2R,3S)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-oxiranyl]-methanol 
• 81520-11-8 (2R,3S,4S)-5-(benzyloxy)-2,4-dimethylpentane-1,3-diol 
• 108393-28-8 (2S,3R,4S)-5-benzyloxy-2,3-dimethylpentane-1,4-diol 
• 155430-54-9 2,2-Dimethyl-propionic acid (3S,4R,5R,6S,7R,8R,9S,10S)-11-benzyloxy-3-hydroxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undecyl ester 
• 155430-52-7 [(2R,3R)-3-((1R,2R,3S,4R,5R,6S,7S)-8-Benzyloxy-1,3,5,7-tetramethyl-2,4,6-tris-triethylsilanyloxy-octyl)-oxiranyl]-methanol 
• 155430-48-1 (E)-3-[(2S,3S)-3-((1S,2S,3R,4S,5S)-6-Benzyloxy-1,3,5-trimethyl-2,4-bis-triethylsilanyloxy-hexyl)-oxiranyl]-acrylic acid ethyl ester 
• 155430-53-8 (3S,4R,5R,6S,7R,8R,9S,10S)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undecane-1,3-diol 
• 155430-46-9 (E)-3-[(2R,3R)-3-((1S,2S,3S)-4-Benzyloxy-1,3-dimethyl-2-triethylsilanyloxy-butyl)-oxiranyl]-acrylic acid ethyl ester 
• 155430-50-5 (E)-(4R,5R,6S,7S,8R,9S,10S)-11-Benzyloxy-5,7,9-trihydroxy-4,6,8,10-tetramethyl-undec-2-enoic acid ethyl ester 
• 155430-49-2 (E)-3-[(2S,3S)-3-((1R,2R,3R,4S,5S)-6-Benzyloxy-2,4-dihydroxy-1,3,5-trimethyl-hexyl)-oxiranyl]-acrylic acid ethyl ester 
• 618096-10-9 (E)-(4S,5R,6S)-7-Benzyloxy-4,6-dimethyl-5-triethylsilanyloxy-hept-2-enoic acid ethyl ester 
• 155613-08-4 (E)-(4S,5S,6S,7S,8S)-9-Benzyloxy-5,7-dihydroxy-4,6,8-trimethyl-non-2-enoic acid ethyl ester 
• 155430-47-0 (E)-3-[(2R,3R)-3-((1R,2S,3S)-4-Benzyloxy-2-hydroxy-1,3-dimethyl-butyl)-oxiranyl]-acrylic acid ethyl ester 

Relevant articles and documents

Synthetic Studies on Polypropionate Antibiotics Based on the Stereospecific Methylation of γ,δ-Epoxy Acrylates by Trimethylaluminum. A Highly Stereoselective Construction of the Eight Contiguous Chiral Centers of Ansa-chains of Rifamycins

A highly stereoselective construction of the eight contiguous chiral centers of ansa-chains of rifamycins has been accomplished by the iterative use of the stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum which was recently developed