618120-15-3Relevant articles and documents
Biomimetic enantioselective total synthesis of (-)-siccanin via the Pd-catalyzed asymmetric allylic alkylation (AAA) and sequential radical cyclizations
Trost, Barry M.,Shen, Hong C.,Surivet, Jean-Philippe
, p. 12565 - 12579 (2007/10/03)
(-)-Siccanin (1), a natural product possessing significant antifungal properties, was synthesized enantioselectively via a biomimetic route. This synthetic route features two sequential radical cyclizations: a Ti(III)-mediated radical cyclization of epoxy