61865-50-7

Basic information

• Product Name: ACETAMIDE
• Synonyms: LABOTEST-BB LT00795814;AMIDE C2;ACETIC ACID AMIDE;(1R,4S)-rel-N-[4-[(Acetyloxy)Methyl]-2-cyclopenten-1-yl]acetaMide;((1S,4R)-4-acetaMidocyclopent-2-enyl)Methyl acetate;cis-(+/-)-N-[4-[(Acetyloxy)Methyl]-2-cyclopenten-1-yl]-acetaMide;AcetaMide,N-[(1R,4S)-4-[(acetyloxy)Methyl]-2-cyclopenten-1-yl]-, rel-
• CAS NO: 61865-50-7
• Molecular Formula: C₁₀H₁₅NO₃
• Molecular Weight: 59.07
• EINECS: 200-473-5
• Product Categories: Intermediates & Fine Chemicals;Pharmaceuticals
• Mol File: 61865-50-7.mol
• Article Data: 2

Chemical Properties

• Melting Point: 78-80 °C(lit.)
• Boiling Point: 221 °C(lit.)
• Appearance: /
• Vapor Pressure: 1 mm Hg ( 65 °C)
• Solubility: H2O: 0.5 g/mL, Hazen ≤50
• CAS DataBase Reference: ACETAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: ACETAMIDE(61865-50-7)
• EPA Substance Registry System: ACETAMIDE(61865-50-7)

Safety Data

• Hazard Codes: Xn
• Statements: 40
• Safety Statements: 36/37
• RIDADR: UN 3077 9/PG 3
• WGK Germany: 1
• RTECS: AB4025000
• F: 3
• Hazardous Substances Data: 61865-50-7(Hazardous Substances Data)

Usage

Chemical Properties

Off-White Solid

Upstream product

• 108-24-7 acetic anhydride 
• 65942-42-9 N-((1R,4S)-4-Hydroxymethyl-cyclopent-2-enyl)-acetamide 
• 49805-30-3 2-azabicyclo[2.2.1.]hept-5-en-3-one 
• 61865-62-1 cis-4-aminocyclopent-2-nene-1-carboxylic acid hydrochloride 
• 77745-25-6 cis-4-amino-2-cyclopentenecarboxylic acid methyl ester hydrochloride 
• 77745-28-9 cis-4-Aminocyclopent-2-enemethanol Hydrochloride 

Downstream Products

• 65898-98-8 Acetic acid 3-acetylamino-cyclopentylmethyl ester 
• 452324-48-0 (+/-)-cis-endo-(4-amino-bicyclo[3.1.0]hex-2-yl)methanol 
• 122624-75-3 (+/-)-cis-<4-<<2-amino-6-chloro-5-<(4-chlorophenyl)azo>-4-pyrimidinyl>amino>-2-cyclopentenyl>carbinol 
• 122624-79-7 (+/-)-cis-<4-(5-amino-7-chloro-3H-1,2,3-triazolo<4,5-d>pyrimidin-3-yl)-2-cyclopentenyl>carbinol 
• 122624-81-1 (+/-)-cis-5-amino-3,6-dihydro-3-<4-(hydroxymethyl)-2-cyclopentenyl>-7H-1,2,3-triazolo<4,5-d>pyrimidin-7-one 
• 122624-83-3 (+/-)-cis-<4-(5,7-diamino-3H-1,2,3-triazolo<4,5-d>pyrimidin-3-yl)-2-cyclopentenyl>carbinol 
• 118237-88-0 (+/-)-cis-<4-(2,6-diamino-9H-purin-9-yl)-2-cyclopentenyl>carbinol 
• 118353-05-2 (+/-)-cis-2-amino-1,9-dihydro-9-[4-(hydroxymethyl)-2-cyclopenten-1-yl]-6H-purin-6-one 
• 122624-71-9 (+/-)-cis-<3-(5,7-diamino-3H-1,2,3-triazolo<4,5-d>pyrimidin-3-yl)cyclopentyl>carbinol 
• 118237-87-9 cis-(+/-)-2-Amino-6-chloro-9-<4-(hydroxymethyl)-2-cyclopenten-1-yl>-9H-purine 
• 122624-82-2 (+/-)-cis-5-amino-3,6-dihydro-3-<3-(hydroxymethyl)cyclopentyl>-1,2,3-triazolo<4,5-d>pyrimidin-7-one 
• 122624-80-0 (+/-)-cis-<3-(5-amino-7-chloro-3H-1,2,3-triazolo<4,5-d>pyrimidin-3-yl)cyclopentyl>carbinol 
• 118237-86-8 (+/-)-cis-<3-(2-amino-6-chloro-9H-purin-9-yl)cyclopentyl>carbinol 
• 112915-00-1 (+/-)-cis-2-amino-1,9-dihydro-9-<3-(hydroxymethyl)cyclopent-1-yl>-6H-purin-6-one 

Relevant articles and documents

Biocatalytical Transformations- VI. The 4-Acetamido-cyclopent-2-ene Carboxylate Route Revisited: Synthesis of (+)- and (-)-Aristeromycin

Enantiomerically pure (+)-as well as (-)-aristeromycin can be synthesized starting from (+)- or (-)-butyl (or hexyl) 4-acetamido-cyclopent-2-ene carboxylate; these carboxylates are easily obtained from their corresponding racemates by hydrolysis with the lipase from Candida rugosa.