62045-89-0

Upstream product

• 122-01-0 4-chloro-benzoyl chloride 
• 71849-99-5 (+/-)-α-phenylglycine hydrochloride 
• 2835-06-5 phenylglycin 
• 22979-35-7 Methyl phenyldiazoacetate 
• 619-56-7 4-chlorobenzamide 

Downstream Products

• 125700-27-8 α-methoxy-N-(4-chlorobenzoyl)-phenylglycine methyl ester 
• 62046-01-9 (4-chloro-benzoylamino)-phenyl-acetic acid 3-methyl-but-2-enyl ester 
• 62045-83-4 1-(p-chlorophenyl)-4-methyl-3-penten-1-one 
• 62045-65-2 2-(4-chlorophenyl)-2-(3,3-dimethylallyl)-4-phenyl-5(2H)-oxazolone 

Relevant academic research and scientific papers

N—H Insertion Reactions Catalyzed by a Dirhodium Metal-Organic Cage: A Facile and Recyclable Approach for C—N Bond Formation

A heterogeneous metal-organic cage based on Rh-Rh bonds [Rh4(pbeddb)4(H2O)2(DMAC)2] (MOC-18; pbeddb2? = 3,3'-(1,3-phenylenebis(ethyne-2,1-diyl))dibenzoate) was applied to the N—H insertion

INDIRECT ELECTROCHEMICAL α-METHOXYLATION OF N-ACYL AND N-CARBOALKOXY α-AMINO ACID ESTERS AND APPLICATION AS CATIONIC GLYCINE EQUIVALENTS

Indirect electrochemical methoxylation of N-acyl and N-carboalkoxy α-amino acid esters in α-position to nitrogen is possible, if chloride is used as mediator.The course of the reaction depends upon the protecting group as well as upon the amino acid side-chain.Increased electron withdrawing effects of the protecting group are accelerating the reaction.On the other hand aliphatic side-chains are diminishing the reactivity.High chloride ion concentrations improve the current yields surprisingly strong.