62134-57-0

Basic information

• Product Name: Cyclohexanamine, N-(2-chloro-2-methylpropylidene)-, (E)-
• CAS NO: 62134-57-0
• Molecular Formula: C10H18ClN
• Molecular Weight: 187.713
• Mol File: 62134-57-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclohexanamine, N-(2-chloro-2-methylpropylidene)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanamine, N-(2-chloro-2-methylpropylidene)-, (E)-(62134-57-0)
• EPA Substance Registry System: Cyclohexanamine, N-(2-chloro-2-methylpropylidene)-, (E)-(62134-57-0)

Safety Data

• Hazardous Substances Data: 62134-57-0(Hazardous Substances Data)

Upstream product

• 917-93-1 2-chloroisobutyraldehyde 
• 108-91-8 cyclohexylamine 
• 144395-93-7 3-(1-Chloro-1-methyl-ethyl)-2-cyclohexyl-oxaziridine 
• 78-84-2 isobutyraldehyde 

Downstream Products

• 144395-93-7 3-(1-Chloro-1-methyl-ethyl)-2-cyclohexyl-oxaziridine 
• 153333-72-3 [2-Azido-2-methyl-prop-(E)-ylidene]-cyclohexyl-amine 
• 55611-45-5 N-(2-methylallyl)cyclohexanamine 
• 42198-07-2 1-cyclohexyl-4,4-dimethyl-imidazolidine-2-thione 
• 1636-29-9 N²-cyclohexyl-1,1-dimethyl-ethanediyldiamine 
• 144396-06-5 2-(N-Cyclohexylamino)-2-methylpropanal 
• 62134-76-3 Cyclohexyl-(2,2-dimethoxy-1,1-dimethyl-ethyl)-amine 
• 62134-69-4 N-(2-methyl-2-propen-1-ylidene)cyclohexylamine 
• 127106-00-7 Cyclohexyl-[2-methyl-2-phenyl-prop-(E)-ylidene]-amine 
• 33950-57-1 Cyclohexyl-[2-methyl-1-phenyl-prop-(Z)-ylidene]-amine 
• 62134-88-7 (E)-N-cyclohexyl-2,2-dimethylpropan-1-imine 

Relevant articles and documents

Rearrangement of 4-(1-haloalkyl)- and 4-(2-haloalkyl)-2-azetidinones into methyl ω-alkylaminopentenoates via transient aziridines and azetidines

The synthesis of 4-(1-haloalkyl)-2-azetidinones and 4-(2-haloalkyl)-2- azetidinones was investigated with use of the Staudinger reaction between in situ generated ketenes and α-haloimines or β-haloimines. This new class of functionalized 2-azetidinones was further evaluated for its potential use as intermediates in the synthesis of highly functionalized compounds. The reaction of 4-(1-haloalkyl)-2-azetidinones and 4-(2-haloalkyl)-2-azetidinones with sodium methoxide in methanol yielded ring-opened products, i.e., methyl 2-alkoxy-4-(alkylamino)pentenoate and methyl 5-(alkyl-amino)pentenoate, respectively. Further attention was paid in detail to the reaction mechanism involved in this peculiar transformation. It was proven that these reactions proceeded via intermediate aziridines or azetidines.