6221-88-1

Usage

Uses

Used in Surface Modification:
(dodecyloxy)(trimethyl)silane is used as a surface modifier to alter the properties of materials, such as improving their hydrophobicity, adhesion, and resistance to environmental factors.
Used in Silicon-Containing Material Synthesis:
In the chemical industry, (dodecyloxy)(trimethyl)silane is used as a key component in the synthesis of various silicon-containing materials, contributing to the development of new products with unique properties.
Used as a Coupling Agent:
(dodecyloxy)(trimethyl)silane serves as a coupling agent, facilitating the bonding between different materials and enhancing the overall performance of formulations such as coatings, adhesives, and sealants.
Used as an Adhesion Promoter:
It is also utilized as an adhesion promoter to improve the bonding strength between different materials, ensuring a more durable and long-lasting connection.
Used in Protective Coatings:
(dodecyloxy)(trimethyl)silane is used as a protective coating for materials such as glass and metal surfaces, providing a barrier against corrosion, wear, and other forms of degradation.
Used in Industrial and Research Applications:
Due to its ability to modify surface properties and improve the performance characteristics of materials, (dodecyloxy)(trimethyl)silane is often used in both industrial and research applications, where its unique properties can be leveraged for the development of innovative products and solutions.

Upstream product

• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 151-41-7 sulfuric acid monododecyl ester 
• 112-53-8 1-dodecyl alcohol 
• 145178-53-6 2,3-bis(trimethylsilyl)-1,3-butadiene-1,4-dione 
• 3482-63-1 n-dodecyl methyl ether 
• 73296-31-8 phenyltellurotrimethylsilane 
• 3385-94-2 hexamethyldisilathiane 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 112-53-8 1-dodecyl alcohol 
• 112-66-3 lauryl acetate 
• 6221-93-8 1-dodecyl propionate 

Relevant academic research and scientific papers

Alkoxide-Induced Succinate Ester Formation from Alcohols and Bis(trimethylsilyl) 1,2-Bisketene

Reaction of the 1,2-bisketene (Me3SiC=C=O)2 (1) with alcohols (ROH) catalyzed by LiOR gives rapid and efficient conversion to mixtures of the meso and dl succinates (Me3SiCHCO2R)2 (4). There is a chan

Alum: An efficient catalyst for trimethylsilylation of alcohols and phenols with hexamethyldisilazane

A highly convenient method for the trimethylsilylation of alcohols and phenols via treatment by hexamethyldisilazane in the presence of alum as a catalyst has been developed. A wide variety of hydroxyl groups were selectively protected in CH3CN under mild conditions.

Melamine-trisulfonic-acid-catalyzed trimethylsilylation of alcohols and phenols

A highly convenient method for the trimethylsilylation of alcohols and phenols via treatment by hexamethyldisilazane in the presence ofmelamine trisulfonic acid as a catalyst has been developed. A wide variety of hydroxyl groups were selectively protected under solvent-free conditions. Copyright Taylor & Francis Group, LLC.

Rapid and efficient trimethylsilyl protection of hydroxyl groups catalyzed by niobium(V) chloride

An efficient and convenient procedure for the trimethylsilylation of a wide variety of alcohols, including primary, benzylic, secondary, and phenols with hexamethyldisilazane, has been developed. The reactions were carried out at room temperature in the presence of a catalytic amount of niobium(V) chloride and afforded the corresponding trimethylsilyl ethers in high to excellent yields in short time. Copyright Taylor & Francis Group, LLC.

Catalyst-free silylation of alcohols and phenols by promoting HMDS in CH3NO2 as solvent

An uncatalyzed method for the silylation of alcohols and phenols with HMDS in CH3NO2 at rt is developed. A diverse range of aromatic and aliphatic alcohols as well as phenols undergo the silylation in very short reaction time with ex

Facile method for trimethylsilylation of alcohols using hexamethyldisilazane and ammonium thiocyanate under neutral conditions

A highly efficient method for trimethylsilylation of primary, secondary, tertiary, allylic, and a variety of sugar-derived alcohols using hexamethyldisilazane in the presence of a catalytic amount of ammonium thiocyanate under neutral conditions is reported. Copyright Taylor & Francis Group, LLC.

Deoxygenative dimerization of benzylic and allylic alcohols, and their ethers and esters using lanthanum metal and chlorotrimethylsilane in the presence of a catalytic amount of iodine and copper(I) iodide

Benzylic and allylic alcohols were deoxygenatively dimerized by a treatment with lanthanum metal and chlorotri-methylsilane in the presence of a catalytic amount of iodine, giving the corresponding coupling products, alkanes, in moderate-to-good yields. This dimerization reaction was dramatically accelerated by the addition of a catalytic amount of copper(I) iodide. Similarly, ethers and esters were deoxygenatively dimerized by La/Me3SiCl/cat.I2/cat.CuI system in the presence of a catalytic amount of H2O.

Liquid-Crystalline D-Glucose Dialkyl Acetals and Dodecyl D-Glucofuranosides

Two new systems of liquid crystalline glucose derivatives 5a-d, 6a, b are prepared, studied and compared with reference compounds.The α- and β-D-dodecyl glucofuranosides 6a, b show smectic A phases.The clearing points of the furanosides are of the same magnitude as those of the pyranosides.The alkyl glucose acetals 5a-d show columnar discotic phases.The clearing points are about 30 deg C lower than those of the corresponding thioacetals. - Key Words: Acetals / Amphiphiles / Carbohydrates / Glucosides / Liquid crystals

A Novel Regioselective Desulfation Method Specific to Carbohydrate 6-Sulfate Using Silylating Reagents

Sulfated primary alcohols and methyl α-D-galactopyranoside 6-sulfate were converted into desulfated and trimethylsilylated alcohols and galactoside, respectively, by treating their pyridinium salts with N,O-bis(trimethylsilyl)acetamide (BTSA) or N,O-bis(trimethylsilyl)trifluoroacetamide (BTSTFA) in pyridine.Sulfated secondary alcohols and methyl galactoside 2-, 3-, and 4-sulfates did not have their sulfates eliminated under similar conditions, indicating that the reaction was specific to the primary hydroxyl groups.Methyl α-galactoside 2-sulfate was preparatively obtained by the BTSA treatment of methyl α-galactoside 2,6-disulfate, that the method is applicable to regioselective desulfation on a preparative scale.

NUCLEOPHILIC CLEAVAGES OF ESTERS AND ETHERS WITH PHENYLTELLUROTRIMETHYLSILANE

The title tellurosilane 1 reacted with esters and ethers in the presence of catalytic zinc iodide under very mild conditions, giving the corresponding products with C-telluration and O-silylation via nucleophilic cleavages of the C-O bonds.