6221-88-1Relevant articles and documents
Alkoxide-Induced Succinate Ester Formation from Alcohols and Bis(trimethylsilyl) 1,2-Bisketene
Egle, Ian,Lai, Wing-Yan,Moore, Patrick A.,Renton, Paul,Tidwell, Thomas T.,Zhao, Da-Chuan
, p. 18 - 25 (1997)
Reaction of the 1,2-bisketene (Me3SiC=C=O)2 (1) with alcohols (ROH) catalyzed by LiOR gives rapid and efficient conversion to mixtures of the meso and dl succinates (Me3SiCHCO2R)2 (4). There is a chan
Melamine-trisulfonic-acid-catalyzed trimethylsilylation of alcohols and phenols
Wu, Liqiang,Sun, Pengli,Yan, Fulin
experimental part, p. 2055 - 2060 (2011/11/30)
A highly convenient method for the trimethylsilylation of alcohols and phenols via treatment by hexamethyldisilazane in the presence ofmelamine trisulfonic acid as a catalyst has been developed. A wide variety of hydroxyl groups were selectively protected under solvent-free conditions. Copyright Taylor & Francis Group, LLC.
Catalyst-free silylation of alcohols and phenols by promoting HMDS in CH3NO2 as solvent
Kadam, Santosh T.,Kim, Sung Soo
supporting information; experimental part, p. 94 - 98 (2010/05/18)
An uncatalyzed method for the silylation of alcohols and phenols with HMDS in CH3NO2 at rt is developed. A diverse range of aromatic and aliphatic alcohols as well as phenols undergo the silylation in very short reaction time with ex