622832-76-2

Upstream product

• 124-63-0 methanesulfonyl chloride 
• 622832-71-7 (1R,2R,3S,4S,5S)-2,3,4-tris(benzyloxy)-5-hydroxy-7-aza-8-oxabicyclo[4.3.0]non-6-ene 
• 622832-73-9 (2R,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-(tert-butyl-dimethyl-silanyloxy)-6-hydroxymethyl-cyclohexanone 
• 622832-72-8 (1R,2R,3S,4S,5S)-2,3,4-tris(benzyloxy)-5-(tert-butyldimethylsiloxy)-7-aza-8-oxabicyclo[4.3.0]non-6-ene 
• 622832-74-0 (1R,2S,3S,4S,5R,6S)-3,4,5-tris(benzyloxy)-6-(hydroxymethyl)cyclohexane-1,2-diol 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 73111-14-5 3,4,5-tris(benzyloxy)-2-(bromomethyl)-6-methoxytetrahydro-2H-pyran 
• 100-39-0 benzyl bromide 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 73111-58-7 2,3,4-tri-O-benzyl-5,6-dideoxy-D-xylo-hex-5-enose 
• 7177-79-9 methyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 157761-58-5 ((1R,2R,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-7-oxabicyclo-[4.1.0]heptan-2-yl)methanol (+)-2,3,4-tri-O-benzylcyclophellitol 

Relevant academic research and scientific papers

Conversion of D-Glucose to Cyclitol with Hydroxymethyl Substituent via Intramolecular Silyl Nitronate Cycloaddition Reaction: Application to Total Synthesis of (+)-Cyclophellitol

(Matrix presented). A diastereoisomeric mixture of 1-nitro-6-heptene-2,3,4, 5-tetraol derivative (A) was prepared by Henry reaction between D-glucose-based aldehyde and nitromethane. Only the (2S)-isomer of A led to cyclitol (B) via nitronate-olefin cyclo