623-19-8Relevant academic research and scientific papers
Preparation method of alkyl carboxylic acid furfuryl ester
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Paragraph 0026-0036; 0045-0050, (2021/11/27)
The invention discloses a preparation method of alkyl carboxylic acid furfuryl ester and relates to furfuryl alcohol. The catalyst, the acylating agent, the acid binding agent and the solvent are uniformly mixed to obtain the alkyl carboxylic acid furfuryl ester compound. The method is high in selectivity, few in byproducts and mild in reaction condition, and has a certain industrial application prospect.
Preparation method of furfuryl alcohol ester
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Paragraph 0028-0029; 0034-0035, (2021/02/10)
The invention discloses a preparation method of furfuryl alcohol ester. The preparation method comprises the following step: subjecting furfural, a bifunctional catalyst, an acylation reagent and a solvent to reacting under hydrogen pressure to obtain furfuryl alcohol ester. The method provided by the invention has the advantages of high selectivity, few byproducts, mild reaction conditions and certain industrial application prospect.
Preparation method of alkyl furfuryl alcohol ester
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Paragraph 0030-0031; 0042-0043, (2020/12/31)
The invention discloses a preparation method of alkyl furfuryl alcohol ester, which comprises the following step of reacting furfuryl alcohol, an esterification catalyst, an acylation reagent, an acid-binding agent and a solvent to obtain the alkyl furfuryl alcohol ester. The method provided by the invention has the advantages of high selectivity, few byproducts, mild reaction conditions and certain industrial application prospect.
HMF and furfural: Promising platform molecules in rhodium-catalyzed carbonylation reactions for the synthesis of furfuryl esters and tertiary amides
Qi, Xinxin,Zhou, Rong,Ai, Han-Jun,Wu, Xiao-Feng
, p. 215 - 221 (2019/11/25)
A biomass involved rhodium-catalyzed carbonylative synthesis of furfuryl esters and tertiary amides has been developed. 5-Hydroxymethylfurfural (HMF) was used as both substrate and CO surrogate for the first time in a carbonylation reaction, and both alkyl and aryl iodides were tolerated well to afford the desired furfuryl esters in moderate to good yields. In addition, furfural was also utilized as a CO source for the synthesis of tertiary amides. A variety of tertiary amides were obtained in moderate to excellent yields with good functional groups compatibility. Notably, tertiary amines were used as the amine source through a C[sbnd]N bond cleavage pathway in the absence of additional oxidant.
