62435-72-7 Usage
Description
METHYL 2,5-DIHYDRO-2,5-DIMETHOXY-2-FURANCARBOXYLATE, also known as Methyl 2,5-dihydro-2,5-dimethoxyfuran-2-carboxylate, is an organic compound that is formed during the electrochemical dimethoxylation of methyl-2-furoate in a ceramic electrochemical microreactor. It exhibits colorless to light yellow liquid properties and is characterized by its unique chemical structure and properties.
Uses
Used in Chemical Synthesis:
METHYL 2,5-DIHYDRO-2,5-DIMETHOXY-2-FURANCARBOXYLATE is used as a key intermediate in the synthesis of various organic compounds and pharmaceuticals. Its unique structure allows it to be a versatile building block for the development of new molecules with potential applications in various industries.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, METHYL 2,5-DIHYDRO-2,5-DIMETHOXY-2-FURANCARBOXYLATE is used as a starting material for the synthesis of drug candidates with potential therapeutic properties. Its ability to be modified and incorporated into complex molecular structures makes it a valuable component in the development of new medications.
Used in Flavor and Fragrance Industry:
METHYL 2,5-DIHYDRO-2,5-DIMETHOXY-2-FURANCARBOXYLATE is also used in the flavor and fragrance industry as a component in the creation of unique scents and flavors. Its distinct chemical properties contribute to the development of novel and appealing sensory experiences in various consumer products.
Used in Electrochemical Research:
In the field of electrochemistry, METHYL 2,5-DIHYDRO-2,5-DIMETHOXY-2-FURANCARBOXYLATE serves as a subject of study for understanding the mechanisms and optimization of electrochemical reactions. Its formation in ceramic electrochemical microreactors provides insights into the development of more efficient and sustainable chemical synthesis processes.
Check Digit Verification of cas no
The CAS Registry Mumber 62435-72-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,2,4,3 and 5 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 62435-72:
(7*6)+(6*2)+(5*4)+(4*3)+(3*5)+(2*7)+(1*2)=117
117 % 10 = 7
So 62435-72-7 is a valid CAS Registry Number.
InChI:InChI=1/C8H12O5/c1-10-6-4-5-8(12-3,13-6)7(9)11-2/h4-6H,1-3H3/t6-,8+/m1/s1
62435-72-7Relevant articles and documents
Asymmetric homogeneous hydrogenation of 2,5-disubstituted furans
Feiertag, Petra,Albert, Martin,Nettekoven, Ulrike,Spindler, Felix
, p. 4133 - 4135 (2006)
A homogeneous catalyst system for the asymmetric cis-hydrogenation of 2,5-disubstituted furans leading to 2′,3′-dideoxynucleoside analogues is described. Best enantioselectivities (ee values of up to 72%) were obtained with cationic rhodium complexes ligated by diphospholanes of the butiphane family. The selectivity of the hydrogenation was reversed by the addition of a base or a polar protic solvent in certain cases. Ferrocene- and proline-based systems gave significant, but lower, ee values.
A new concept for the preparation of beta-L- and beta-D-2',3'-dideoxynucleoside analogues.
Albert, Martin,De Souza, Dominic,Feiertag, Petra,Hoenig, Helmut
, p. 3251 - 3254 (2007/10/03)
[reaction: see text] A new method for the synthesis of 2',3'-dideoxynucleoside analogues has been developed. An electrochemical activation of 2-substituted furans is followed by the coupling with a pyrimidine or purine base. This gives planar furyl nucleosides as key intermediates, which are hydrogenated cis-selectively to give the corresponding beta-2',3'-dideoxynucleosides as racemic mixtures. An enzymatic kinetic resolution gives rise to beta-D- and beta-L-configured derivatives in high optical purity. This is exemplified by the synthesis of beta-D- and beta-L-3'-deoxythymidine.
Nitronium Acetate Adducts of Furan Derivatives
Balina, Gisela,Kesler, Patricia,Petre, Janet,Pham, Dung,Vollmar, Arnulf
, p. 3811 - 3818 (2007/10/02)
An improved procedure for the isolation of the main addition products of the reaction between nitronium acetate and furfural diacetate or methyl 2-furoate is described.The kinetics of the deacetylation of the diastereomeric 1,4-adducts in buffer solutions revealed a substantial primary hydrogen isotope effect.Mild acid-induced alcoholysis transformed the adducts into 2,5-dialkoxy-2,5-dihydrofurans.The reaction chemistry of the furan adducts is compared with the solvolytic pathways reported for ipso nitronium acetate adducts formed from alkylbenzenes.
