6244-75-3

Basic information

• Product Name: 4-chloro-N-phenylbenzenecarbothioamide
• CAS NO: 6244-75-3
• Molecular Formula: C₁₃H₁₀ClNS
• Molecular Weight: 247.7432
• Mol File: 6244-75-3.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 355.9°C at 760 mmHg
• Flash Point: 169.1°C
• Density: 1.316g/cm³
• Vapor Pressure: 3.02E-05mmHg at 25°C
• Refractive Index: 1.703
• CAS DataBase Reference: 4-chloro-N-phenylbenzenecarbothioamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-chloro-N-phenylbenzenecarbothioamide(6244-75-3)
• EPA Substance Registry System: 4-chloro-N-phenylbenzenecarbothioamide(6244-75-3)

Safety Data

• Hazardous Substances Data: 6244-75-3(Hazardous Substances Data)

Upstream product

• 6833-15-4 4-chlorobenzanilide 
• 133218-29-8 p-Chloro-N-(3-phenylpropionyl)thiobenzanilide 
• 39153-42-9 p-Chlor-dithiobenzoesaeure-p-chlorphenylester 
• 62-53-3 aniline 
• 20849-33-6 phenyl p-chlorobenzenedithiocarboxylate 
• 165543-77-1 4-Chloro-dithiobenzoic acid p-tolyl ester 
• 165543-78-2 4-Chloro-dithiobenzoic acid 4-bromo-phenyl ester 
• 104-88-1 4-chlorobenzaldehyde 
• 122-01-0 4-chloro-benzoyl chloride 

Downstream Products

• 61522-25-6 2-(4-chloro-phenyl)-5-ethoxycarbonyl-4-oxo-3-phenyl-4,5-dihydro-thiazolium betaine 
• 6265-91-4 2-(4-chlorophenyl)benzothiazole 
• 6833-15-4 4-chlorobenzanilide 
• 136169-25-0 C₂₀H₁₇ClN₄S 
• 136169-34-1 C₂₀H₁₇ClN₄O 
• 133218-29-8 p-Chloro-N-(3-phenylpropionyl)thiobenzanilide 
• 136169-38-5 C₁₃H₁₂ClN₃ 
• 52730-98-0 2-(4-Chlorphenyl)-3,5-diphenyl-1,3-thiazolium-4-olat 
• 52730-97-9 2-(4-chloro-phenyl)-4-oxo-3-phenyl-4,5-dihydro-thiazolium betaine 
• 55712-14-6 2-(4-chloro-phenyl)-4,6-dioxo-3,5-diphenyl-5,6-dihydro-4H-[1,3]thiazinium betaine 

Relevant articles and documents

Visible-Light Carbon Nitride-Catalyzed Aerobic Cyclization of Thiobenzanilides under Ambient Air Conditions

A metal-free heterogeneous photocatalysis has been developed for the synthesis of benzothiazoles via intramolecular C-H functionalization/C-S bond formation of thiobenzanilides by inexpensive graphitic carbon nitride (g-C3N4) under visible-light irradiation. This reaction provides access to a broad range of 2-substituted benzothiazoles in high yields under an air atmosphere at room temperature without addition of a strong base or organic oxidizing reagents. In addition, the catalyst was found to be stable and reusable after five reaction cycles.

Synthesis of thioamides by catalyst-free three-component reactions in water

Three-component reactions involving amines, aldehydes, and elemental sulfur powder are reported to afford thioamides in a simple one-pot procedure in the absence of a catalyst. A variety of thioamides can be obtained in good to excellent yields up to 88 %. Three-component reactions involving amines, aldehydes, and sulfur powder afford thioamides in a simple one-pot procedure. A variety of substituted thioamides are obtained in good to excellent yields up to 88 %. Copyright

Palladium-catalyzed synthesis of 2-substituted benzothiazoles via a C-H functionalization/intramolecular C-S bond formation process

(Chemical Equation Presented) Catalytic synthesis of 2-substituted benzothiazoles from thiobenzanilides was achieved in the presence of a palladium catalyst through C-H functionalization/C-S bond formation. This method features the use of a novel catalytic system consisting of 10 mol % of Pd(II), 50 mol % of Cu(I), and 2 equiv of Bu4NBr that produced variously substituted benzothiazoles in high yields with good functional group tolerance.