62460-99-5

Basic information

• Product Name: Benzenesulfonic acid, 4-methyl-, (1-phenylethylidene)hydrazide, (E)-
• CAS NO: 62460-99-5
• Molecular Formula: C15H16N2O2S
• Molecular Weight: 288.37
• Mol File: 62460-99-5.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Benzenesulfonic acid, 4-methyl-, (1-phenylethylidene)hydrazide, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonic acid, 4-methyl-, (1-phenylethylidene)hydrazide, (E)-(62460-99-5)
• EPA Substance Registry System: Benzenesulfonic acid, 4-methyl-, (1-phenylethylidene)hydrazide, (E)-(62460-99-5)

Safety Data

• Hazardous Substances Data: 62460-99-5(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 536-74-3 phenylacetylene 
• 119072-54-7 2,6-dimethylphenyl isonitrile 
• 119072-55-8 tert-butylisonitrile 
• 931-53-3 Cyclohexyl isocyanide 

Downstream Products

• 98-86-2 acetophenone 
• 907997-19-7 2-phenyl-1,4-pentadien-3-ol 
• 1421692-91-2 (E)-4-methyl-N-(1-phenylethyl)-N'-(1-phenylethylidene)benzenesulfonohydrazide 
• 73130-06-0 3-phenyl-1-(toluene-4-sulfonyl)-1H-pyrazole 
• 2458-26-6 3-phenylpyrazole 
• 1450753-92-0 (E)-4-nitro-N-[2-{1-(2-tosylhydrazono)ethyl}phenyl]benzamide 
• 530-48-3 1,1-Diphenylethylene 
• 92-52-4 biphenyl 
• 4333-75-9 1-(4-methoxyphenyl)-1-phenylethene 
• 29265-81-4 1-chloro-3-(1-phenylvinyl)benzene 
• 1220985-74-9 C₁₅H₁₂⁽²⁾H₂O 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 

Relevant articles and documents

I2-Promoted [4 + 2] cycloaddition of: In situ generated azoalkenes with enaminones: Facile and efficient synthesis of 1,4-dihydropyridazines and pyridazines

A facile and efficient strategy for the synthesis of 1,4-dihydropyridazines and pyridazines through I2-promoted [4 + 2] cycloaddition of in situ generated azoalkenes with enaminones has been developed. The switch in selectivity is attributed to the judici

Rh(iii)-catalyzed alkynylation: Synthesis of functionalized quinolines from aminohydrazones

Rhodium-catalyzed, chemo- and regioselective synthesis of functionalized quinolines using 2-aminohydrazones and terminal alkynes has been described. The reaction is oxidant/base-free and tolerates a wide variety of functional groups and has been successfu

Diversity-Orientated Stereoselective Synthesis through Pd-Catalyzed Switchable Decarboxylative C?N/C?S Bond Formation in Allylic Surrogates

Switchable catalytic transformation of reactants can be a powerful approach towards diversity-orientated synthesis from easily available molecular synthons. Herein, an endogenous ligand-controlled, Pd-catalyzed allylic substitution allowing for either selective C?N or C?S bond formation using vinylethylene carbonates (VECs) and N-sulfonylhydrazones as coupling partners has been developed. This versatile methodology provides a facile, divergent route for the highly chemo- and stereoselective synthesis of functional allylic sulfones or sulfonohydrazides. The newly developed protocol features wide substrate scope (nearly 80 examples), broad functional group tolerance, and potential for the late-stage functionalization of bioactive compounds. The isolation and crystallographic analysis of a catalytically competent π-allyl Pd complex suggests that the pathway leading to the allylic products proceeds through a different manifold as previously proposed for the functionalization of VECs with nucleophiles.