62498-73-1Relevant academic research and scientific papers
Anagostic, mono- and hexahapta interactions in Tl(I) dithiocarbamates: A new precursor for the preparation of Tl2S nanoparticles
Gomathi, Govindaraju,Thirumaran, Subbiah,Ciattini, Samuele
, p. 424 - 433 (2015/11/11)
Two new homoleptic complexes, [Tl(bzfdtc)]2 (1) and [Tl(bu2-OHbzdtc)]2 (2) (where bzfdtc = N-benzyl-N-furfuryldithiocarbamate and bu2-OHbzdtc = (N-butyl-N-(2-hydroxybenzyl)dithiocarbamate), have been prepared an
Carbon dioxide as a carbonylating agent in the synthesis of 2-oxazolidinones, 2-oxazinones, and cyclic ureas: Scope and limitations
Paz, Jairo,Perez-Balado, Carlos,Iglesias, Beatriz,Munoz, Luis
experimental part, p. 3037 - 3046 (2010/07/15)
Carbon dioxide can be used as a convenient carbonylating agent in the synthesis of 2-oxazolidinones, 2-oxazinones, and cyclic ureas. The transient carbamate anion generated by treating a primary or secondary amine group in basic media can be activated with phosphorylating agents such as Diphenylphosphoryl azide (DPPA) and Diphenyl chlorophosphate (DPPCl) but also with other types of electrophiles such as SOCl2, TsCl, or AcCl. The intramolecular trapping of the activated carbamate by a hydroxyl group leads to the formation of 2-oxazolidinones or 2-oxazinones in good to excellent yields. This methodology was successfully applied to the synthesis of cyclic ureas up to 7-membered rings from the corresponding diamines.
A reductive amination of carbonyls with amines using decaborane in methanol
Bae, Jong Woo,Lee, Seung Hwan,Cho, Young Jin,Yoon, Cheol Min
, p. 145 - 146 (2007/10/03)
Aldehydes and ketones were easily converted to the corresponding amines by the reaction of amines in methanol using decaborane (B10H14) at room temperature under nitrogen. The reaction is simple and efficient. The Royal Society of Chemistry 2000.
An Efficient Synthesis of Highly Functionalized Unsymmetrical Biphenyls Having Substituents on the Ortho Positions
Takahashi, Masami,Moritani, Yasunori,Ogiku, Tsuyoshi,Ohmizu, Hiroshi,Kondo, Kazuhiko,Iwasaki, Tameo
, p. 5103 - 5104 (2007/10/02)
The highly functionalized unsymmetrical biphenyls having electron-donating and/or electron-withdrawing substituents on the ortho positions were effectively synthesized based on the intramolecular Ullmann coupling reaction directed by salicyl alcohol as a
