6252-00-2

Basic information

• Product Name: phenyl-(2-phenyl-1,3-dioxolan-2-yl)methanone
• Synonyms: phenyl-(2-phenyl-1,3-dioxolan-2-yl)methanone
• CAS NO: 6252-00-2
• Molecular Formula: C₁₆H₁₄O₃
• Molecular Weight: 254.28
• Mol File: 6252-00-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 397°C at 760 mmHg
• Flash Point: 185.5°C
• Appearance: /
• Density: 1.208g/cm³
• Vapor Pressure: 1.63E-06mmHg at 25°C
• Refractive Index: 1.59
• CAS DataBase Reference: phenyl-(2-phenyl-1,3-dioxolan-2-yl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl-(2-phenyl-1,3-dioxolan-2-yl)methanone(6252-00-2)
• EPA Substance Registry System: phenyl-(2-phenyl-1,3-dioxolan-2-yl)methanone(6252-00-2)

Safety Data

• Hazardous Substances Data: 6252-00-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H14O3/c17-15(13-7-3-1-4-8-13)16(18-11-12-19-16)14-9-5-2-6-10-14/h1-10H,11-12H2

Upstream product

• 5694-69-9 phenyl-(2-phenyl-[1,3]dioxolan-2-yl)-methanol 
• 4344-45-0 5,6-Diphenyl-2,3-dihydro-[1,4]dioxine 
• 2446-83-5 di-isopropyl azodicarboxylate 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 107-21-1 ethylene glycol 
• 501-65-5 diphenyl acetylene 

Relevant articles and documents

Method for visible light driven green synthesis of benzoin bis-ether

The invention relates to a method for visible light driven green synthesis of benzoin bis-ether. The method comprises the steps that an alkyne compound, an alcohol compound and 10-methyl-9-sym-trimethylbenzene based acridine perchlorate perform driving reaction in the atmosphere at room temperature with the visible light with the wavelength of 450-460 nm, a reaction solution is obtained after 3 hours and is spin-dried to obtain concentrate, and the concentrate is subjected to column chromatography on silica gel to obtain the benzoin bis-ether. The method is high in yield, moderate in conditionand small in environmental pollution.

Reactions of α-Hydroxy Carbonyl Compounds with Azodicarboxylates and Triphenylphosphine: Synthesis of α-N-Hydroxy Amino Acid Derivatives

Reaction of aliphatic α-hydroxy esters with azodicarboxylates and triphenylphosphine in the presence of either CbzNHOCH2Ph or trOCNHOCH2Ph provides a direct route to protected α-N-hydroxy amino acids.Similar reactions with aromatic α-hydroxy carbonyl compounds and derivatives result in predominate oxidation to the corresponding α-oxo carbonyl derivatives.

OXIDATION OF ALCOHOLS TO CARBONYL COMPOUNDS WITH CHROMIUM(V) REAGENTS

Two pentavalent chromium complexes have been used effectively for the oxidation of alcohols to carbonyl compounds.