6263-62-3

Basic information

• Product Name: BENZYL ETHYL SULPHIDE
• Synonyms: [(Ethylsulfanyl)methyl]benzene;1-Phenyl-2-thiabutane;alpha-(Ethylthio)toluene;benzene,[(ethylthio)methyl]-;Benzyl ethyl sulfide;benzylethylsulfide;Ethyl benzyl sulfide;ethylbenzylsulfide
• CAS NO: 6263-62-3
• Molecular Formula: C₉H₁₂S
• Molecular Weight: 152.26
• EINECS: 228-422-2
• Mol File: 6263-62-3.mol
• Article Data: 40

Chemical Properties

• Boiling Point: 234.76°C (estimate)
• Flash Point: 78.7°C
• Appearance: /
• Density: 1.0120 (estimate)
• Vapor Pressure: 0.185mmHg at 25°C
• Refractive Index: 1.5493 (estimate)
• CAS DataBase Reference: BENZYL ETHYL SULPHIDE(CAS DataBase Reference)
• NIST Chemistry Reference: BENZYL ETHYL SULPHIDE(6263-62-3)
• EPA Substance Registry System: BENZYL ETHYL SULPHIDE(6263-62-3)

Safety Data

• Safety Statements: S24/25:Avoid contact with skin and eyes.
• Hazardous Substances Data: 6263-62-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 34, p. 1323, 1986 DOI: 10.1248/cpb.34.1323Synthesis, p. 66, 1987 DOI: 10.1055/s-1987-27849

InChI:InChI=1/C9H12S/c1-2-10-8-9-6-4-3-5-7-9/h3-7H,2,8H2,1H3

Upstream product

• 74-96-4 ethyl bromide 
• 3492-64-6 sodium benzylmercaptide 
• 60-29-7 diethyl ether 
• 3012-37-1 benzyl thiocyanate 
• 925-90-6 ethylmagnesium bromide 
• 1708-73-2 chloromethyl ethyl sulfide 
• 688-62-0 triethyl trithiophosphite 
• 100-44-7 benzyl chloride 
• 100-53-8 phenylmethanethiol 
• 80-40-0 ethyl ester of p-toluenesulfonic acid 
• 41795-82-8 S-benzyl thioacetimidate hydrobromide 
• 62652-30-6 2-(ethylthio)benzo[d]oxazol 
• 100-51-6 benzyl alcohol 
• 7334-52-3 benzaldehyde diethyldithioacetal 

Downstream Products

• 76354-15-9 diethyl-benzyl sulfonium ; ethyl sulfate 
• 101169-02-2 (α-Benzoyloxy-benzyl)-aethyl-sulfid 
• 28295-59-2 (R)-((ethylsulfinyl)methyl)benzene 
• 70286-60-1 (S)- ((ethylsulfinyl)methyl)benzene 
• 100-52-7 benzaldehyde 
• 18542-39-7 ethyl ethanethiosulfinate 
• 772-47-4 benzyl ethyl sulfone 
• 28295-59-2 benzyl ethyl sulfoxide 
• 95419-51-5 cis-{PtCl₂(PPh₃)(C₆H₅CH₂SC₂H₅)} 
• 60175-20-4 pentacarbonyl(ethylsulfanylmethylbenzene)chromium 
• 4445-34-5 dibenz(C,E)oxepin-5(7H)-one 
• 165287-65-0 (benzyl ethyl sulfide)trichlorogold(III) 
• 1137737-53-1 S-benzyl-S-ethyl-N-(benzyloxycarbonyl)-sulfilimine 
• 75490-48-1 1,2-diphenylethyl ethyl sulfide 

Relevant articles and documents

Catenation of 2,2'-Bis(ethylthiomethyl)biphenyl with Copper(I) Bromide

Treatment of 2-(ethylthiomethyl)phenyllithium with copper(I) bromide afforded a polymeric coordination compound in which 2,2'-bis(ethylthiomethyl)biphenyl molecules were linked by copper(I) bromide cores.This polymeric complex dissociates on dissolution in organic solvents and reforms on recrystalization from the solution.Other copper(I) salts also gave similar compounds, when reacted with the lithium compound.

Palladium- and Nickel-Catalyzed Decarbonylative C-S Coupling to Convert Thioesters to Thioethers

This Letter describes the development of a catalytic decarbonylative C-S coupling reaction that transforms thioesters into thioethers. Both Pd- and Ni-based catalysts are developed and applied to the construction of diaryl, aryl alkyl, and heterocycle-containing thioethers.

Iodine-mediated thioetherification of alcohols with disulfides or NaSh under microwave irradiation

An efficient and novel method for the thioetherification of an alcohol with disulfides or NaSH under microwave irradiation is presented. In the presence of iodine, a variety of alcohols were smoothly S-alkylated with disulfides or NaSH to give the corresponding thioethers in moderate to excellent yields. Copyright