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3012-37-1

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3012-37-1 Usage

Description

Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.

Chemical Properties

ALMOST WHITE TO YELLOW CRYSTALS OR CRYST. POWDER

Uses

Different sources of media describe the Uses of 3012-37-1 differently. You can refer to the following data:
1. Benzyl Thiocyanate is found to increase the protein production of Streptomyces aureofaciens. Inhibits methylazoxymethanol acetate-induced intestinal carcinogenesis and reduces unscheduled DNA synthesi s for some genotoxic carcinogens in rats.
2. Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.

Application

Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.

Synthesis Reference(s)

Synthesis, p. 184, 1977Tetrahedron Letters, 18, p. 4417, 1977 DOI: 10.1016/S0040-4039(01)83524-3

General Description

Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.

Hazard

Strong irritant to skin, tissue. Moderate fire hazard.

Safety Profile

Poison by subcutaneous andintraperitoneal routes. Whenheated to decomposition it emits very toxic fumes ofNOx, SOx, and CN??.

Purification Methods

Crystallise the thiocyanate from EtOH or aqueous EtOH. [Beilstein 6 H 460, 6 IV 2680.]

Check Digit Verification of cas no

The CAS Registry Mumber 3012-37-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,0,1 and 2 respectively; the second part has 2 digits, 3 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 3012-37:
(6*3)+(5*0)+(4*1)+(3*2)+(2*3)+(1*7)=41
41 % 10 = 1
So 3012-37-1 is a valid CAS Registry Number.
InChI:InChI=1/C8H7NS/c9-7-10-6-8-4-2-1-3-5-8/h1-5H,6H2

3012-37-1 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • TCI America

  • (T0198)  Benzyl Thiocyanate  >99.0%(GC)

  • 3012-37-1

  • 25g

  • 170.00CNY

  • Detail
  • TCI America

  • (T0198)  Benzyl Thiocyanate  >99.0%(GC)

  • 3012-37-1

  • 500g

  • 1,350.00CNY

  • Detail
  • Alfa Aesar

  • (B23902)  Benzyl thiocyanate, 98+%   

  • 3012-37-1

  • 50g

  • 356.0CNY

  • Detail
  • Alfa Aesar

  • (B23902)  Benzyl thiocyanate, 98+%   

  • 3012-37-1

  • 250g

  • 1118.0CNY

  • Detail
  • Aldrich

  • (13929)  Benzylthiocyanate  ≥95.0% (GC)

  • 3012-37-1

  • 13929-100G

  • 589.68CNY

  • Detail

3012-37-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name benzyl thiocyanate

1.2 Other means of identification

Product number -
Other names Benzyl thiocyanate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3012-37-1 SDS

3012-37-1Relevant articles and documents

Inorganic-Solid-Supported Potassium Thiocyanate: Study of Reagent Preparation and a Convenient Synthesis of tert-Alkyl Thiocyanates

Ando, Takashi,Clark, James H.,Cork, David G.,Fujita, Mitsue,Kimura, Takahide

, p. 681 - 685 (1987)

-

AIBN-initiated direct thiocyanation of benzylic sp3C-H with: N -thiocyanatosaccharin

Wu, Di,Duan, Yongjie,Liang, Kun,Yin, Hongquan,Chen, Fu-Xue

supporting information, p. 9938 - 9941 (2021/10/12)

Direct thiocyanations of benzylic compounds have been implemented. Here, a new strategy, involving a free radical reaction pathway initiated by AIBN, was used to construct the benzylic sp3 C-SCN bond. In this way, the disadvantage of other strategies involving introducing leaving groups in advance to synthesize benzyl thiocyanate compounds was overcome. The currently developed protocol also involved the use of readily available raw materials and resulted in high product yields (up to 100%), both being great advantages for synthesizing benzyl thiocyanates.

Thiocyanation and 2-Amino-1,3-thiazole Formation in Water Using Recoverable and Reusable Glycosylated Resorcin[4]arene Cavitands

Husain, Ali A.,Bisht, Kirpal S.

, p. 9928 - 9935 (2020/09/03)

A family of three spatially directional resorcin[4]arene cavitand glycoconjugates (RCGs) have been applied as efficient recoverable and reusable inverse phase transfer catalysts for eco- A nd environmentally friendly thiocyanation and 2-amino-1,3-thiazole formation reactions in water. The results show that RCGs (1 mol %) were capable of hosting and catalyzing various water-insoluble bromo/thiocyanato substrates in water without the use of any co-organic solvents. The recoverability and reusability of RCG catalytic systems, that is, RCG1 and RCG3, were also examined upon a simple extraction of the desired products using DCM or ethyl acetate, followed by subjecting the recovered aqueous solution containing the RCG catalysts to the next reaction cycles.

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