627079-62-3

Upstream product

• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 627079-61-2 (2E,4E,6E,8E)-2,4,6,8-tetramethyl-9-(4-nitrophenyl)nona-2,4,6,8-tetraenal 
• 627079-60-1 ethyl (2E,4E,6E,8E)-2,4,6,8-tetramethyl-9-(4-nitrophenyl)nona-2,4,6,8-tetraenoate 
• 648414-22-6 (2E,4E,6E,8E)-2,4,6,8-Tetramethyl-9-(4-nitro-phenyl)-nona-2,4,6,8-tetraen-1-ol 
• 476418-12-9 ethyl (2E,4E,6E)-2,4,6-trimethyl-7-(4-nitrophenyl)hepta-2,4,6-trienoate 
• 648414-16-8 (2E,4E,6E)-2,4,6-trimethyl-7-(4-nitrophenyl)hepta-2,4,6-trien-1-ol 
• 78847-04-8 (2E,4E,6E)-2,4,6-trimethyl-7-(4-nitro-phenyl)-hepta-2,4,6-trienal 
• 58550-34-8 (E)-2-methyl-3-(4-nitrophenyl)acrylaldehyde 
• 555-16-8 4-nitrobenzaldehdye 
• 53618-29-4 (E)-ethyl 2-methyl-3-(4-nitrophenyl)acrylate 
• 59488-85-6 (2E,4E)-2,4-dimethyl-5-(4-nitrophenyl)penta-2,4-dienol 
• 59488-84-5 (2E,4E)-2,4-dimethyl-5-(p-nitrophenyl)pentan-2,4-dienal 
• 22388-91-6 ethyl (2E,4E)-2,4-dimethyl-5-(4-nitrophenyl)penta-2,4-dienoate 
• 37542-81-7 (2E)-2-methyl-3-(4-nitrophenyl)prop-2-en-1-ol 

Relevant academic research and scientific papers

Biomimetic studies on polyenes.

The crispatenes and SNF4435 C&D are complex polypropionate derived natural products. The core structures of these compounds along with a complex unnatural structure can be easily prepared from a common polyene precursor simply by variation of the reaction conditions. The reaction pathways provide insight into the biosynthesis of these complex natural products.

Mechanistic evidence supporting the biosynthesis of photodeoxytridachione

This letter describes a two-step photochemical rearrangement of a conjugated pentaene. The results provide evidence that the marine product photodeoxytridachione is formed in two sequential photochemical reactions.