62839-71-8

Basic information

• Product Name: Benzene, 1-decenyl-, (E)-
• CAS NO: 62839-71-8
• Molecular Formula: C16H24
• Molecular Weight: 216.367
• Mol File: 62839-71-8.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Benzene, 1-decenyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-decenyl-, (E)-(62839-71-8)
• EPA Substance Registry System: Benzene, 1-decenyl-, (E)-(62839-71-8)

Safety Data

• Hazardous Substances Data: 62839-71-8(Hazardous Substances Data)

Upstream product

• 103-64-0 bromostyrene 
• 3314-49-6 octyllithium 
• 62839-72-9 (Z)-1-(dec-1-enyl)benzene 
• 591-50-4 iodobenzene 
• 872-05-9 1-Decene 
• 66348-67-2 benzyl 2-pyrimidine sulfide 
• 93222-35-6 1-Methoxy-(E)-1-decene 
• 124-19-6 nonan-1-al 
• 14156-61-7 2-<(phenylmethyl)sulfonyl>pyridine 
• 144708-17-8 2-<(phenylmethyl)sulfonyl>pyrimidine 
• 30089-00-0 9-octyl-9-bora-bicyclo[3.3.1]nonane 
• 588-72-7 [(E)-2-bromoethenyl]benzene 
• 111-83-1 1-bromo-octane 
• 588-73-8 (Z)-β-bromostyrene 

Relevant articles and documents

Pd-catalyzed oxidative Heck-type arylation of vinyl ketones, alkenes, and acrylates with Sb-aryl-tetrahydrodibenz[c,f][1,5]azastibocines

The Pd-catalyzed cross-coupling reactions of Sb-aryl-1,5-azastibocines with alkenes are described. The reactions of azastibocines with alkenes such as vinyl ketones, alkenes, and acrylates in the presence of 10 mol% PdCl2 at 80 °C in DMA under aerobic conditions produced Heck adducts in moderate-to-excellent yields. Single-crystal X-ray and NMR analysis revealed that the aryl donors in this reaction, the Sb-aryl-1,5-azastibocines, are hypervalent compounds that display N–Sb intramolecular non-bonding interaction. These are the first examples of Pd-catalyzed Heck-type arylations using heterocyclic hypervalent organoantimony compounds. Although the reactions proceeded efficiently with the azastibocines, they hardly progressed with trivalent and pentavalent triarylantimony reagents.

Metal-Catalyzed Remote Functionalization of ω-Ene Unsaturated Ethers: Towards Functionalized Vinyl Species

The combined ruthenium-catalyzed chain walking with the nickel-catalyzed cross-coupling reaction of ω-alkenyl ethers provide a unique entry to functionalized vinyl species. This transformation illustrates the power and flexibility of remote functionalization by demonstrating the compatibility of two independent reactions involving unrelated sites.

N-Acylsaccharins as Amide-Based Arylating Reagents via Chemoselective N-C Cleavage: Pd-Catalyzed Decarbonylative Heck Reaction

Palladium-catalyzed decarbonylative Heck reaction of amides by chemoselective N-C activation using N-acylsaccharins as coupling partners has been accomplished. These studies represent only the second example of amide-Heck reactions reported to date. A broad range of electronically diverse amide and olefin coupling partners is amenable to this transformation. Orthogonal site-selective Heck cross-couplings by C-Br/N-C cleavage and mechanistic studies are reported. This report introduces readily available, bench-stable, cheap, and benign N-acylsaccharins as aryl transfer reagents to access versatile aryl-metal intermediates.