62839-72-9

Basic information

• Product Name: Benzene, 1-decenyl-, (Z)-
• CAS NO: 62839-72-9
• Molecular Formula: C16H24
• Molecular Weight: 216.367
• Mol File: 62839-72-9.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Benzene, 1-decenyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-decenyl-, (Z)-(62839-72-9)
• EPA Substance Registry System: Benzene, 1-decenyl-, (Z)-(62839-72-9)

Safety Data

• Hazardous Substances Data: 62839-72-9(Hazardous Substances Data)

Upstream product

• 111-83-1 1-bromo-octane 
• 588-73-8 (Z)-β-bromostyrene 
• 30089-00-0 9-octyl-9-bora-bicyclo[3.3.1]nonane 
• 124-19-6 nonan-1-al 
• 144708-17-8 2-<(phenylmethyl)sulfonyl>pyrimidine 
• 14156-61-7 2-<(phenylmethyl)sulfonyl>pyridine 
• 111-66-0 oct-1-ene 
• 103-64-0 bromostyrene 
• 101349-79-5 2-phenylvinyl iodide 
• 3314-49-6 octyllithium 
• 67219-33-4 2-phenylmethanesulfonyl-benzothiazole 
• 764-93-2 1-decyne 
• 108-86-1 bromobenzene 
• 588-72-7 [(E)-2-bromoethenyl]benzene 

Downstream Products

• 62839-71-8 (E)-1-phenyl-1-decene 

Relevant articles and documents

Metal-Catalyzed Remote Functionalization of ω-Ene Unsaturated Ethers: Towards Functionalized Vinyl Species

The combined ruthenium-catalyzed chain walking with the nickel-catalyzed cross-coupling reaction of ω-alkenyl ethers provide a unique entry to functionalized vinyl species. This transformation illustrates the power and flexibility of remote functionalization by demonstrating the compatibility of two independent reactions involving unrelated sites.

Copper-catalyzed alkene arylation with diaryliodonium salts

Alkenes and arenes represent two classes of feedstock compounds whose union has fundamental importance to synthetic organic chemistry. We report a new approach to alkene arylation using diaryliodonium salts and Cu catalysis. Using a range of simple alkenes, we have shown that the product outcomes differ significantly from those commonly obtained by the Heck reaction. We have used these insights to develop a number of new tandem and cascade reactions that transform readily available alkenes into complex arylated products that may have broad applications in chemical synthesis.

Insertion of 1-chloro-1-lithioalkenes into organozirconocenes. A versatile synthesis of stereodefined unsaturated systems

Hydrozirconation of alkenes and alkynes, followed by insertion of 1- halo-1-lithio-1-alkenes, generated in situ by lithium tetramethylpiperidide deprotonation of vinyl halides, affords vinylzirconocene species which may be further elaborated. The method provides easy access to many structures including terminal (3E)- and (3Z)-1,3-dienes and (3E,5E)- and (3Z,5E)-1,3,5- trienes, and internal (E,Z)-dienes,(E,Z,E)-trienes, and (1E, 3Z)1,3-dien-5- ynes. Insertion of 2-monosubstituted 1-halo-1-lithio-1-alkenes occurs with clean inversion of configuration of the sp2-carbenoid carbon. Carbenoids derived by deprotonation of 2,2-disubstituted 1-halo-1-alkenes gave poor stereocontrol probably due to isomerization before insertion into the organozirconium species. Insertion of vinyl carbenoids into alkynylzirconocenes affords terminal (3E)- or (3Z)-1,3-dien-5-ynes, internal (1E,3Z)-1,3-dien-5-ynes, and (Z)-3-en-1,5-diynes.