628686-53-3Relevant academic research and scientific papers
Synthesis of oligoarabinofuranosides from the mycobacterial cell wall
Marotte, Karine,Sanchez, Sylvie,Bamhaoud, Toufiq,Prandi, Jacques
, p. 3587 - 3598 (2007/10/03)
Oligoarabinofuranosides 1-4, fragments of the arabinan components found in the mycobacterial cell wall have been synthesized. 1 and 2 are representative of the structural features of the internal core of arabinogalactan, arabinomannan and lipoarabinomanna
1,2,5-Ortho esters of D-arabinose as versatile arabinofuranosidic building blocks. Concise synthesis of the tetrasaccharidic cap of the lipoarabinomannan of Mycobacterium tuberculosis
Bamhaoud, Toufiq,Sanchez, Sylvie,Prandi, Jacques
, p. 659 - 660 (2007/10/03)
1,2,5-ortho esters of D-arabinose were found to be ideally suited building blocks for the stereoselective formation of and β arabinofuranosidic linkages after nucleophilic opening of the orthoester with oxygen and sulfur nucleophiles; the tetrasaccharidic cap of the lipoarabinomannan of Mycobacterium tuberculosis was then synthesized in a highly convergent manner.
