6293-71-6 Usage
Uses
Used in Organic Synthesis:
Iodonium, bis(4-methoxyphenyl)-, iodide is utilized as a mild oxidizing agent in organic synthesis. Its role in this application is crucial for facilitating various organic reactions, making it a valuable component in the synthesis of complex organic molecules.
Used as a Precursor:
This iodonium salt also serves as a precursor for the preparation of other organic iodine compounds. Its ability to act as a starting material for the synthesis of a range of iodine-containing organic substances underscores its versatility and importance in the field of organic chemistry.
Check Digit Verification of cas no
The CAS Registry Mumber 6293-71-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,2,9 and 3 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 6293-71:
(6*6)+(5*2)+(4*9)+(3*3)+(2*7)+(1*1)=106
106 % 10 = 6
So 6293-71-6 is a valid CAS Registry Number.
6293-71-6Relevant academic research and scientific papers
Synthesis of some n-aryl α-Amino acids using diaryliodonium salts
Mckerrow, Jason D.,Al-Rawi, Jasim M.,Brooks, Peter
experimental part, p. 1227 - 1236 (2012/09/22)
Bis[(3'-methoxycarbonyl)phenyl]iodonium bromide (4a), bis (4'-methoxyphenyl)iodonium iodide (4b) and bis (4'-acetamidophenyl)iodonium iodide (4c) were employed for the first time in the arylation of α-amino acid methyl esters. Yields of the synthesised products 5, 6 and 7 were good to high. These were then hydrolyzed to the corresponding N-aryl α-amino acids 8 and 9. The chiral integrity of the amino acids was maintained throughout the reaction sequence as confirmed by the synthesis of chiral tripeptide 10 and dipeptides 11. The structures of the new compounds were confirmed by IR, 1H and 13C NMR in addition to CHN microanalysis or high resolution mass spectrometry.
