62932-75-6

Upstream product

• 139377-33-6 phenylmethyl 2-[3-(phenylmethoxy)phenyl]acetate 
• 22446-38-4 ethyl 3-hydroxyphenylacetate 
• 1860-58-8 3-benzyloxyphenylacetic acid 
• 621-37-4 m-hydroxyphenylacetic acid 
• 917-54-4 methyllithium 
• 160721-29-9 methyl 2-<3-(benzyloxy)phenyl>-N-methyl acetohydroxamate 
• 130604-43-2 ethyl 3-(benzyloxyphenyl)acetate 

Downstream Products

• 1416136-82-7 2-[3-(benzyloxy)phenyl]-1,1-bis(4-hydroxyphenyl)-1-butene 
• 79755-51-4 1-(3-benzyloxyphenyl)-2-chloropropan 
• 79755-52-5 2-chloro-1-(3-hydroxyphenyl)propane 
• 79755-53-6 1-(3-hydroxyphenyl)prop-1-ene 
• 79755-50-3 1-(3-benzyloxyphenyl)propan-2-ol 
• 64479-84-1 1-(3-hydroxyphenyl)propan-2-one 

Relevant academic research and scientific papers

Regioselective synthesis of 1,8-dihydroxytetralins through a tandem reduction/intramolecular hydroxyalkylation of 4-(3-hydroxyphenyl)alkanoates

A series of 4-(3-hydroxyphenyl)butanoates 3 has been prepared and transformed into 1,8-dihydroxytetralins of general formula 2 by treatment with 2 equivalents of DIBALH followed by quenching with aqueous NH4Cl. A possible mechanism for this novel totally regioselective intramolecular hydroxyalkylation is suggested and the factors affecting the stability of 1,8-dihydroxytetralins 2 are also discussed.

Biosynthesis of Fungal Metabolites. Terrein, a Metabolite of Aspergillus terreus Thom

Terrein, a metabolite of Aspergillus terreus Thom, is biosynthesised from 3,4-dihydro-6,8-dihydroxy-3-methylisocoumarin by contraction of an aryl ring.The direction of the ring contraction has been investigated using acetate as precursor.