6301-60-6Relevant academic research and scientific papers
Strategic end-halogenation of π-conjugated small molecules enabling fine morphological control and enhanced performance of organic solar cells
Furukawa, Seiichi,Yasuda, Takuma
supporting information, p. 14806 - 14815 (2019/06/24)
Organic solar cells based on π-conjugated small molecules (SM-OSCs) have developed rapidly in the past few years. Nevertheless, the design strategies of small-molecule (SM) donors for high-efficiency SM-OSCs require further improvement. Halogenation is an effective way to modulate their electronic properties, and to date, fluorination has been most widely used for the design of organic photovoltaic materials. However, the feasibility and utility of photovoltaic materials incorporating other halogens, especially heavier bromine and iodine, have not been fully explored. Here, a novel family of SM donor materials, having the same π-conjugated backbone but different terminal halogen groups (F, Cl, Br, and I), are systematically designed and developed. Furthermore, the structure-property-function relationships stemming from the variations in the substituted halogen atoms are discussed. Among these end-halogenated SM donors, the I-containing material shows remarkably high photovoltaic performance in the fullerene-based SM-OSCs, demonstrating power conversion efficiencies of up to 9.2% without any processing additives and post-treatment processes. Detailed morphological analyses reveal that end-halogenation with heavier halogen atoms, typified by I and Br, effectively modulated the interfacial free energy of the blend with a fullerene acceptor and facilitate the formation of fine interpenetrating networks in the active layer. This study establishes a new design paradigm featuring end-halogenation for producing high-performance photovoltaic materials for SM-OSCs.
Bisisobenzofurandionylantracene compound, preparation method thereof and organic insulationg layer using the same
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Paragraph 0101; 0102; 0103, (2016/10/10)
The present invention relates to a bis-isobenzofuran-dionyl antracene compound, a manufacturing method thereof and an organic insulation film using the same wherein the bis-isobenzofuran-dionyl antracene compound can be used for manufacturing an organic insulator with high heat resistance. According to the present invention, a manufacturing method of the bis-isobenzofuran-dionyl antracene compound uses suzuki-coupling, which has few limitations for functional groups and high selectivity for reaction and accordingly has few side reactions, dehydration cyclization reaction and hydrolysis under base or acid conditions, thereby manufacturing bis-isobenzofuran-dionyl antracene with improved purity and yield.COPYRIGHT KIPO 2015
A Mild and General One-Pot Synthesis of Densely Functionalized Diaryliodonium Salts
Qin, Linlin,Hu, Bao,Neumann, Kiel D.,Linstad, Ethan J.,McCauley, Katelyenn,Veness, Jordan,Kempinger, Jayson J.,DiMagno, Stephen G.
supporting information, p. 5919 - 5924 (2015/09/22)
Diaryliodonium salts are powerful and widely used arylating agents in organic chemistry. Here we report a scalable synthesis of densely functionalized diaryliodonium salts from aryl iodides under mild conditions. This two-step, one-pot process has remarkable functional group tolerance, is compatible with commonly employed acid-labile protective group strategies, avoids heavy metal and transition metal reagents, and provides a direct route to stable precursors to PET imaging agents.
Iodination of aromatic compounds with iodine and n-butyltriphenylphosphonium peroxodisulfate
Tajik,Esmaeili,Mohammadpoor-Baltork,Ershadi,Tajmehri
, p. 1319 - 1323 (2007/10/03)
Iodine and n-butyltriphenylphosphonium peroxodisulfate can be successfully used for the iodination of some aromatic compounds in acetonitrile as solvent. The yields obtained are good to excellent.
