630104-26-6

Basic information

• Product Name: 1-Triazene, 3,3-diethyl-1-(4-iodophenyl)-
• CAS NO: 630104-26-6
• Molecular Formula: C10H14IN3
• Molecular Weight: 303.146
• Mol File: 630104-26-6.mol

Chemical Properties

• CAS DataBase Reference: 1-Triazene, 3,3-diethyl-1-(4-iodophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Triazene, 3,3-diethyl-1-(4-iodophenyl)-(630104-26-6)
• EPA Substance Registry System: 1-Triazene, 3,3-diethyl-1-(4-iodophenyl)-(630104-26-6)

Safety Data

• Hazardous Substances Data: 630104-26-6(Hazardous Substances Data)

Upstream product

• 53694-87-4 1-azido-4-iodo-benzene 
• 109-89-7 diethylamine 
• 540-37-4 p-aminoiodobenzene 

Downstream Products

• 1139927-79-9 C₄₂H₄₅N₉ 
• 73852-88-7 2-(4-iodophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1327277-69-9 1-(4-(2-(4-bromophenyl)ethynyl)phenyl)-3,3-diethyltriazene 
• 255829-44-8 3,6-di-tert-butyl-9-(4-ethynyl-phenyl)-9H-carbazole 
• 255829-43-7 3,6-di-tert-butyl-9-[4-(trimethylsilylethynyl)phenyl]-9H-carbazole 
• 255829-32-4 3,6-di-tert-butyl-9-(4-iodophenyl)-9H-carbazole 
• 57103-15-8 9-(4-iodophenyl)carbazole 
• 262861-81-4 9-(4-ethynyl-phenyl)-9H-carbazole 

Relevant articles and documents

4-iodophenyl substituted carborane derivative and preparation method thereof

The invention discloses a 4-iodophenyl carborane derivative and a preparation method thereof. Commercialized organic reagents 4-iodoaniline and a diacetonitrile decaborate complex and several easily-synthesized substituted alkynes are adopted as the start

Symmetrically backfolded molecules emulating the self-similar features of a Sierpinski triangle

We synthesized self-similar molecules (G3 and G2; based on phenylalkynyl backbones) with symmetrically backfolded shapes inspired by the famous fractal of a Sierpinski triangle. Unlike the more traditional, starburst dendrimers, the centripetal-shaped Sierpinski molecules feature side branches symmetrically bent away from the growth direction of the main branch, thus contrasting the natural-tree shape. Molecule G3 exhibits three distinct levels of the structural hierarchy comprising the primary, secondary and tertiary branches, while the smaller G2 contains only features of the 1st and 2nd orders. In spite of the much larger conjugated backbone of G3, its solution UV-vis absorption and fluorescence exhibit no red shift relative to G2. In a test of nitrobenzene sensing, a thin film of G3 deposited from THF was more sensitively quenched in fluorescence than the smaller G2.

Synthesis of triazene-substituted homoconjugated push-pull chromophores by formal [2?+?2] cycloadditions

1-(4-Ethynylphenyl)-3,3-dialkyltriaz-1-enes, well-known building blocks for branched dendrimer syntheses, were utilized as a new type of electron-donor component in formal [2 + 2] cycloadditions. The click-type, atom-economic reactions proceed efficiently

Synthesis and photophysical properties of biphenyl and terphenyl arylene-ethynylene macrocycles

A series of single-walled carbon nanotube precursors, C3h- symmetric cyclotri(ethynylene)(biphenyl-2,4′-diyl) and cyclotri(ethynylene)(p-terphenyl-2,4″-diyl), have been prepared by a linear stepwise oligomerization-cyclization route and by stat

Aromatic fluoro-de-triazenation with boron trifluoride diethyl etherate under non-protic acid conditions

Fluoro-de-triazenation of 3,3-diethyl-1-aryltriazenes can be achieved by conventional or under microwave heating in carbon tetrachloride, in the presence of boron trifluoride diethyl etherate without any protic acid to avoid corresponding unwanted byproduct formation.

Rapid solution and solid phase synthesis of monodisperse oligo[(1,4-phenyleneethynylene)-alt-(2,5-thiopheneethynylene)]s

Monodisperse oligo[(1,4-phenyleneethynylene)-alt-(2,5-thiopheneethynylene)] s, new candidates for molecular wires, were rapidly synthesized via an iterative divergent/convergent doubling strategy in solution as well as on Merrifield's resin.

Synthesis of monodisperse oligo[(1,4-phenyleneethynylene)-alt-(2,5- thiopheneethynylene)]s

The synthesis of monodisperse oligo[(1,4-phenyleneethynylene)-alt-(2,5- thioph-eneethynylene)]s using an iterative divergent/convergent doubling strategy based on Sonogashira coupling reaction was presented.

A novel in situ deprotection/coupling and iterative divergent/convergent strategy for the synthesis of oligo(1,4-phenyleneethynylene)s

A novel in situ deprotection/coupling and iterative divergent/convergent strategy for the synthesis of oligo(1,4-phenyleneethynylene)s is described.

Efficient synthesis of a complete donor/acceptor bis(aryl)diyne family

A facile route to a family of bis(aryl)diynes containing both an electron donating pyridine ring and an electron accepting iodobenzene has been developed. The convergent synthesis involves the coupling of 2-, 3-, or 4-bromopyridine with TMS-acetylene, followed by deprotection to form the first half of the molecule. Similarly, 2-, 3-, or 4-iodoaniline was coupled to TMS-acetylene after protection of the amine group as a diethyltriazine. After conversion of the triazine to an iodine, deprotection of the acetylene and formation of the corresponding bromophenyl-acetylene, the two halves of the molecule were coupled under Cadiot-Chodkiewicz conditions. Nine new compounds were prepared, each of which was found to thermally polymerize from the melt. None of the compounds underwent photochemical polymerization in the solid-state.

Creation of nanoscale oxaarenecyclynes and their C60 complexes

Novel nanoscale oxaarenecyclynes (3 and 4) consisting of diethynylbenzene and ether units were synthesized, which form supramolecular complexes with C60.