632339-24-3

Upstream product

• 81132-13-0 (S)-5-phenylmethoxypentane-1,3-diol 
• 77-76-9 2,2-dimethoxy-propane 
• 67-64-1 acetone 
• 19790-60-4 3-Benzyloxypropanal 
• 89923-31-9 (E)-5-(benzyloxy)pent-2-en-1-ol 
• 89956-14-9 [3-(2-Benzyloxyethyl)oxiran-2-yl]methanol 
• 853193-61-0 (-)-(3S,5E)-1-benzyloxyhept-5-en-3-ol 

Downstream Products

• 632339-44-7 2,2-Dimethyl-propionic acid (2E,4Z)-5-{(2R,3S,4S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-4-methyl-penta-2,4-dienyl ester 
• 632339-27-6 (2R,3S,5S)-7-(tert-Butyl-diphenyl-silanyloxy)-1-((1S,5R,7R)-10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-yl)-3,5-dihydroxy-2-methyl-heptan-1-one 
• 632339-42-5 (2E,4Z)-5-{(2R,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-4-methyl-penta-2,4-dienoic acid ethyl ester 
• 632339-43-6 (2E,4Z)-5-{(2R,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-4-methyl-penta-2,4-dien-1-ol 
• 632339-31-2 2-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran-2-ol 
• 632339-38-9 (Z)-3-{(2R,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-2-methyl-acrylic acid ethyl ester 
• 632339-32-3 2-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran 
• 632339-40-3 (Z)-3-{(2R,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-2-methyl-prop-2-en-1-ol 
• 632339-41-4 (Z)-3-{(2R,3S,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-2-methyl-propenal 
• 632339-34-5 {4-(tert-butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-methanol 
• 632339-36-7 4-(tert-butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran-2-carbaldehyde 
• 632339-30-1 4-(tert-butyl-dimethyl-silanyloxy)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-3-methyl-tetrahydro-pyran-2-one 
• 632339-28-7 (2R,3S,5S)-7-(tert-Butyl-diphenyl-silanyloxy)-3,5-dihydroxy-2-methyl-heptanoic acid 
• 632339-29-8 (3R,4S,6S)-6-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-4-hydroxy-3-methyl-tetrahydro-pyran-2-one 

Relevant academic research and scientific papers

Remote asymmetric induction in an intramolecular ionic Diels-Alder reaction: Application to the total synthesis of (+)-dihydrocompactin

The total synthesis of (+)-dihydrocompactin via an intramolecular ionic Diels-Alder reaction that proceeds with remote stereocontrol is described. This reaction proceeds by an intermediate vinyl-oxocarbenium ion (6), the conformational constraints of whic

Enantioselective construction of the C1-C16 segment of lasonolide A

An efficient and enantiocontrolled synthesis of the C1-C 16 segment of lasonolide A has been accomplished starting from a readily available optically pure aldehyde.