632339-24-3Relevant academic research and scientific papers
Remote asymmetric induction in an intramolecular ionic Diels-Alder reaction: Application to the total synthesis of (+)-dihydrocompactin
Sammakia, Tarek,Johns, Deidre M.,Kim, Ganghyeok,Berliner, Martin A.
, p. 6504 - 6505 (2007/10/03)
The total synthesis of (+)-dihydrocompactin via an intramolecular ionic Diels-Alder reaction that proceeds with remote stereocontrol is described. This reaction proceeds by an intermediate vinyl-oxocarbenium ion (6), the conformational constraints of whic
Enantioselective construction of the C1-C16 segment of lasonolide A
Deba, Tatsuya,Yakushiji, Fumika,Shindo, Mitsuru,Shishido, Kozo
, p. 1500 - 1502 (2007/10/03)
An efficient and enantiocontrolled synthesis of the C1-C 16 segment of lasonolide A has been accomplished starting from a readily available optically pure aldehyde.
