81132-13-0Relevant articles and documents
Remote asymmetric induction in an intramolecular ionic Diels-Alder reaction: Application to the total synthesis of (+)-dihydrocompactin
Sammakia, Tarek,Johns, Deidre M.,Kim, Ganghyeok,Berliner, Martin A.
, p. 6504 - 6505 (2007/10/03)
The total synthesis of (+)-dihydrocompactin via an intramolecular ionic Diels-Alder reaction that proceeds with remote stereocontrol is described. This reaction proceeds by an intermediate vinyl-oxocarbenium ion (6), the conformational constraints of whic
Enantioselective construction of the C1-C16 segment of lasonolide A
Deba, Tatsuya,Yakushiji, Fumika,Shindo, Mitsuru,Shishido, Kozo
, p. 1500 - 1502 (2007/10/03)
An efficient and enantiocontrolled synthesis of the C1-C 16 segment of lasonolide A has been accomplished starting from a readily available optically pure aldehyde.
Pigments of fungi. XLIV* synthesis of differentially protected chiral pentane-1,3,5-triol derivatives; confirmation of the absolute configuration of naturally occurring 3-acetoxy-2,3-dihydropiptoporic acid
Burns, Christopher J.,Gill, Melvyn,Saubern, Simon
, p. 1067 - 1079 (2007/10/03)
(R)-1-t-Butyldimethylsilyloxy-5-phenylmethoxypentan-3-ol (25), prepared in 68% yield and >99.9% enantiomeric excess over six steps from commercially available but-3-yn-1-ol by Katsuki-Sharpless epoxidation, was converted by way of its 3-methoxymethyl ethe
Synthesis of Saccharides and Related Polyhydroxylated Natural Products. 2. Simple Deoxyalditols
Ma, P.,Martin, V. S.,Masamune, S.,Sharpless, K. B.,Viti, S. M.
, p. 1378 - 1380 (2007/10/02)
Asymmetric epoxidation of allylic alcohols followed by selective hydride reduction provides a new route to chiral 1,3-diols and 1,3,5-triols; one of the 1,3,5-triols (21) is also synthesized from D-glucose.