63369-67-5

Basic information

• Product Name: 2-methylbenzenesulfinyl chloride
• Synonyms: 2-methylbenzenesulfinyl chloride
• CAS NO: 63369-67-5
• Molecular Weight: 174.651
• Mol File: 63369-67-5.mol

Chemical Properties

• CAS DataBase Reference: 2-methylbenzenesulfinyl chloride(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methylbenzenesulfinyl chloride(63369-67-5)
• EPA Substance Registry System: 2-methylbenzenesulfinyl chloride(63369-67-5)

Safety Data

• Hazardous Substances Data: 63369-67-5(Hazardous Substances Data)

Upstream product

• 10436-57-4 S-(2-methylphenyl) thioacetate 
• 186098-94-2 S-(2-methylphenyl) 2-methylbenzenesulfinothioate 
• 931-59-9 benzenesulfenyl chloride 
• 137-06-4 2-thiocresol 

Downstream Products

• 4032-80-8 bis(2-methylphenyl)disulfide 
• 186098-94-2 S-(2-methylphenyl) 2-methylbenzenesulfinothioate 
• 38045-42-0 S-(2-methylphenyl) 2-methylbenzenesulfonothioate 
• 13165-77-0 toluenesulfinic acid 
• 15898-37-0 sodium 2-methylbenzenesulfinate 

Relevant articles and documents

Visible Light-Promoted Synthesis of β-Keto Sulfoximines from N-Tosyl-Protected Sulfoximidoyl Chlorides

Under visible light, N-tosyl-protected sulfoximidoyl chlorides react with aryl alkynes to give β-keto sulfoximines. The reaction is characterized by a high functional group tolerance and good yields. It can be improved by the presence of a ruthenium photo

The 'Thio-Arbuzov' reaction of sulfenate esters with sulfenyl chlorides: Fate of the thiosulfinate product

The further reaction of thiosulfinate esters (putative products of the 'Thio-Arbuzov' reaction of sulfenate esters with sulfenyl chlorides) with sulfenyl chlorides and sulfenate esters has been studied. In the former case, sulfinyl chlorides and disulfides are formed. In the latter case sulfinate esters and disulfides are obtained. Copyright (C) 1996 Elsevier Science Ltd.

A FACILE SYNTHESIS OF SULFINYL CHLORIDES FROM THIOLACETATES

Alkyl and aryl thiolacetates are converted smoothly into sulfinyl chlorides by sulfuryl chloride in the presence of acetic anhydride.