63489-73-6

Upstream product

• 101325-12-6 1-(4-tert-butylphenyl)ethanol 
• 75-36-5 acetyl chloride 
• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 7364-19-4 4-ethyl-tert-butylbenzene 

Downstream Products

• 392727-87-6 1-(4-tert-butyl-2-nitrophenyl)ethyl acetate 
• 3282-56-2 4-tert-butylnitrobenzene 
• 101325-12-6 1-(4-tert-butylphenyl)ethanol 
• 119436-49-6 1-(1-bromoethyl)-4-(tert-butyl)benzene 

Relevant academic research and scientific papers

Benzylic-acetoxylation of alkylbenzenes with PhI(OAc)2 in the presence of catalytic amounts of TsNH2 and I2

Treatment of alkylbenzenes with (diacetoxyiodo)benzene in the presence of catalytic amounts of p-toluenesulfonamide or p-nitrobenzenesulfonamide, and molecular iodine in 1,2-dichloroethane at 60 °C gave the corresponding (α-acetoxy)alkylbenzenes in good to moderate yields. The present reaction is a simple method for the introduction of an acetoxy group to the benzylic position of alkylbenzenes.

Synthesis of o-nitrosoacylbenzenes from o-nitrobenzyl alcohols and their derivatives

Nitration of substituted benzyl alcohols, as well as ethers and esters derived therefrom, with nitric acid in acetic anhydride was studied. The corresponding o-nitrobenzyl alcohols and their derivatives formed as the primary products are capable of being converted into o-nitrosoacylbenzenes by the action of acids. Pleiades Publishing, Inc., 2006.

Benzylthio pyridazinone derivatives, preparation thereof, and insecticidal acaricidal, fungicidal compositions

Novel 3(2H)-pyridazinone derivatives having the formula I: STR1 wherein, R is a straight or branched C2 to C6 alkyl, R1 and R2 are each independently hydrogen or a lower alkyl, R4 is a halogen, R3 is a halogen, an alkyl, a cycloalkyl, an alkoxy, a haloalkyl, a haloalkoxy, --CN, --NO2, a phenyl, a benzyloxy, a benzyl, a phenoxy, a phenylthio, a pyridyloxy, a quinoxalyloxy, a lower alkenyloxy, a lower alkylthio, a lower haloalkylthio, --Si(CH3)3, --OH, --N(CH3)2, --SCN, --COOCH3 or --OCH(CH3)COOC2 H5, and n is an integer of 1 to 5, said R3 being the same or different when n is an integer of 2 to 5. A process for preparation of said derivatives is also provided. These derivatives are useful as an active ingredient of insecticidal, acaricidal, nematicidal and/or fungicidal compositions for agricultural and horticultural uses as well as of expellent compositions for ticks parasitic on animals.