63603-16-7

Upstream product

• 71001-78-0 3-nitro-4-chloro-5-methoxybenzoic acid 
• 3943-74-6 4-hydroxy-3-methoxybenzoic acid methyl ester 
• 63603-09-8 methyl 4-chloro-3-methoxy-5-nitrobenzoate 
• 42590-00-1 4-hydroxy-3-methoxy-5-nitrobenzoic acid methyl ester 

Downstream Products

• 71650-90-3 2-trimethylsilyl-ethyl N-methyl-(5-bromo-2-chloro-anisol-1-yl)-carbamat 
• 71653-15-1 2-chloro-3-[N-methyl-(2-trimethylsilyl-ethyl)-carbamato]-5-(5-bromo-2-methyl-(E,E)-2,4-pentadienyl)-anisole 
• 71650-89-0 (5-Bromo-2-chloro-3-methoxy-phenyl)-carbamic acid 2-trimethylsilanyl-ethyl ester 
• 71694-86-5 (5-Bromo-2-chloro-3-methoxy-phenyl)-carbamic acid phenyl ester 
• 86117-47-7 [({2-Chloro-5-[(2E,4E)-(6R,9S,10R)-9-(1-ethoxy-ethoxy)-7,7-bis-ethylsulfanyl-10-((2S,3R)-3-formyl-3-methyl-oxiranyl)-6-methoxy-2-methyl-undeca-2,4-dienyl]-3-methoxy-phenyl}-methyl-carbamoyl)-methyl]-phosphonic acid diethyl ester 
• 86116-97-4 C₄₅H₈₀ClNO₈S₂Si₂ 
• 86046-99-3 C₄₄H₇₈ClNO₈S₂Si₂ 
• 86046-99-3 C₄₄H₇₈ClNO₈S₂Si₂ 
• 52978-28-6 (-)-maysine 
• 72729-16-9 {(2S,3S)-3-[(6E,8E)-(1R,2S,5R)-10-(4-Chloro-3-methoxy-5-methylamino-phenyl)-2-(1-ethoxy-ethoxy)-4,4-bis-ethylsulfanyl-5-methoxy-1,9-dimethyl-deca-6,8-dienyl]-2-methyl-oxiranyl}-methanol 
• 86117-46-6 (2R,3S)-3-[(6E,8E)-(1R,2S,5R)-10-(4-Chloro-3-methoxy-5-methylamino-phenyl)-2-(1-ethoxy-ethoxy)-4,4-bis-ethylsulfanyl-5-methoxy-1,9-dimethyl-deca-6,8-dienyl]-2-methyl-oxirane-2-carbaldehyde 

Relevant academic research and scientific papers

Total synthesis of (-)-maysine

A convergent synthesis of the natural macrocycle (-)-maysine (3) has been accomplished involving only a single separation of epimers at C-10. The scheme involved the preparation of three major fragments: (a) the western zone, 4; (b) the southern zone, 6;