72729-16-9

Basic information

• Product Name: {(2S,3S)-3-[(6E,8E)-(1R,2S,5S)-10-(4-Chloro-3-methoxy-5-methylamino-phenyl)-2-(1-ethoxy-ethoxy)-4,4-bis-ethylsulfanyl-5-methoxy-1,9-dimethyl-deca-6,8-dienyl]-2-methyl-oxiranyl}-methanol
• CAS NO: 72729-16-9
• Molecular Weight: 660.38
• Mol File: 72729-16-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {(2S,3S)-3-[(6E,8E)-(1R,2S,5S)-10-(4-Chloro-3-methoxy-5-methylamino-phenyl)-2-(1-ethoxy-ethoxy)-4,4-bis-ethylsulfanyl-5-methoxy-1,9-dimethyl-deca-6,8-dienyl]-2-methyl-oxiranyl}-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: {(2S,3S)-3-[(6E,8E)-(1R,2S,5S)-10-(4-Chloro-3-methoxy-5-methylamino-phenyl)-2-(1-ethoxy-ethoxy)-4,4-bis-ethylsulfanyl-5-methoxy-1,9-dimethyl-deca-6,8-dienyl]-2-methyl-oxiranyl}-methanol(72729-16-9)
• EPA Substance Registry System: {(2S,3S)-3-[(6E,8E)-(1R,2S,5S)-10-(4-Chloro-3-methoxy-5-methylamino-phenyl)-2-(1-ethoxy-ethoxy)-4,4-bis-ethylsulfanyl-5-methoxy-1,9-dimethyl-deca-6,8-dienyl]-2-methyl-oxiranyl}-methanol(72729-16-9)

Safety Data

• Hazardous Substances Data: 72729-16-9(Hazardous Substances Data)

Upstream product

• 86046-99-3 C₄₄H₇₈ClNO₈S₂Si₂ 
• 74-88-4 methyl iodide 
• 86116-97-4 C₄₅H₈₀ClNO₈S₂Si₂ 
• 86046-99-3 C₄₄H₇₈ClNO₈S₂Si₂ 
• 72729-14-7 (4S,5R)-5-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-3-methyl-oxiranyl]-4-(1-ethoxy-ethoxy)-2,2-bis-ethylsulfanyl-hexanal 
• 71694-86-5 (5-Bromo-2-chloro-3-methoxy-phenyl)-carbamic acid phenyl ester 
• 71650-89-0 (5-Bromo-2-chloro-3-methoxy-phenyl)-carbamic acid 2-trimethylsilanyl-ethyl ester 
• 71653-12-8 (2E,4E)-5-bromo-2-methyl-penta-2,4-dienoic acid ethyl ester 
• 86046-94-8 (E,E)-1,5-dibromo-2-methyl-2,4-pentadiene 
• 71653-13-9 (E,E)-1-hydroxy-2-methyl-5-bromo-2,4-pentadiene 
• 72729-13-6 (3S,4R)-4-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-3-methyl-oxiranyl]-3-(1-ethoxy-ethoxy)-pentanedithioic acid ethyl ester 
• 86046-98-2 (2R,3S,4S)-(-)-5-tert-butyldimethylsilyloxy-3,4-epoxy-2,4-dimethylpentyl benzyl ether 
• 80885-47-8 (R)-(+)-5-benzyloxy-2,4-dimethyl-(E)-2-pentenal 
• 80925-22-0 (R)-(+)-5-benzyloxy-2,4-dimethyl-(E)-2-pentenol 

Downstream Products

• 52978-28-6 (-)-maysine 
• 86117-47-7 [({2-Chloro-5-[(2E,4E)-(6R,9S,10R)-9-(1-ethoxy-ethoxy)-7,7-bis-ethylsulfanyl-10-((2S,3R)-3-formyl-3-methyl-oxiranyl)-6-methoxy-2-methyl-undeca-2,4-dienyl]-3-methoxy-phenyl}-methyl-carbamoyl)-methyl]-phosphonic acid diethyl ester 
• 86117-46-6 (2R,3S)-3-[(6E,8E)-(1R,2S,5R)-10-(4-Chloro-3-methoxy-5-methylamino-phenyl)-2-(1-ethoxy-ethoxy)-4,4-bis-ethylsulfanyl-5-methoxy-1,9-dimethyl-deca-6,8-dienyl]-2-methyl-oxirane-2-carbaldehyde 

Relevant articles and documents

Total synthesis of (-)-maysine

A convergent synthesis of the natural macrocycle (-)-maysine (3) has been accomplished involving only a single separation of epimers at C-10. The scheme involved the preparation of three major fragments: (a) the western zone, 4; (b) the southern zone, 6;