63904-73-4Relevant articles and documents
Remote sp2C-H Carboxylation via Catalytic 1,4-Ni Migration with CO2
B?rjesson, Marino,Duan, Yaya,Janssen-Müller, Daniel,Martin, Ruben,Sahoo, Basudev,Wang, Xueqiang
supporting information, p. 16234 - 16239 (2020/10/09)
A remote catalytic reductive sp2 C-H carboxylation of arenes with CO2 (1 bar) via 1,4-Ni migration is disclosed. This protocol constitutes the first catalytic 1,4-Ni migration reported to date, thus offering new vistas in the Ni-catalyzed reductive coupling arena while providing an unconventional new platform for incorporating electrophilic sites at remote sp2 C-H linkages.
Photochemical Properties of cis- and trans-1,2-Diphenylethyltrimethyltin(IV) and cis-1,2-Diphenylpropenyltrimethyltin(IV): Organometallic Derivatives of Stilbene
Kelly, John M.,Trautman, Raymond J.
, p. 909 - 914 (2007/10/02)
Upon direct u.v. irradiation in cyclohexane, benzene, alcohol, or chloroform slution, (1) undergoes cis-trans isomerisation about the olefin double bond as the only reaction.No evidence has been found for either homolytic or heterolytic