63987-52-0

Basic information

• Product Name: Benzoic acid, 3-chloro-, phenylMethyl ester
• Synonyms: Benzoic acid, 3-chloro-, phenylMethyl ester
• CAS NO: 63987-52-0
• Molecular Formula: C₁₄H₁₁ClO₂
• Molecular Weight: 246.68894
• Mol File: 63987-52-0.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzoic acid, 3-chloro-, phenylMethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 3-chloro-, phenylMethyl ester(63987-52-0)
• EPA Substance Registry System: Benzoic acid, 3-chloro-, phenylMethyl ester(63987-52-0)

Safety Data

• Hazardous Substances Data: 63987-52-0(Hazardous Substances Data)

Upstream product

• 2905-65-9 methyl 3-chlorobenzoate 
• 587-04-2 m-Chlorobenzaldehyde 
• 100-51-6 benzyl alcohol 
• 100-44-7 benzyl chloride 
• 108-88-3 toluene 
• 535-80-8 3-chlorobenzoate 
• 100-39-0 benzyl bromide 
• 16518-11-9 meta-chlorobenzoic acid potassium salt 

Downstream Products

• 535-80-8 3-chlorobenzoate 
• 620-47-3 1-methyl-3-(phenylmethyl)-benzene 
• 620-83-7 1-methyl-4-(phenylmethyl)benzene 
• 713-36-0 2-benzyltoluene 

Relevant articles and documents

Convenient synthesis of benziodazolone: New reagents for direct esterification of alcohols and amidation of amines

Hypervalent iodine heterocycles represent one of the important classes of hypervalent iodine reagents with many applications in organic synthesis. This paper reports a simple and convenient synthesis of benziodazolones by the reaction of readily available iodobenzamides with m-chloroperoxybenzoic acid in acetonitrile at room temperature. The structure of one of these new iodine heterocycles was confirmed by X-ray analysis. In combination with PPh3 and pyridine, these benziodazolones can smoothly react with alcohols or amines to produce the corresponding esters or amides of 3-chlorobenzoic acid, respectively. It was found that the novel benziodazolone reagent reacts more efficiently than the analogous benziodoxolone reagent in this esterification.

NOVEL SINGLE STEP ESTERIFICATION PROCESS OF ALDEHYDES USING A HETEROGENEOUS CATALYST

The present invention relates to a novel simple, efficient and single-step process for esterification of aldehydes using a heterogeneous catalyst with high yields. More particularly, the present invention relates to a novel simple, efficient and single-step process for esterification of aldehydes using Titanium superoxide with greater than 80% yields.

Palladium-catalyzed benzylation of carboxylic acids with toluene via benzylic C-H activation

Direct benzylation of carboxylic acids with toluene has been developed via palladium-catalyzed C-H acyloxylation under 1 atm of oxygen. This reaction demonstrates good functional group tolerance and high yields, providing a facile, atom-economic, and efficient method for the synthesis of benzyl esters.