64097-92-3

Basic information

• Product Name: 2-(1-phenylethenyl)aniline
• Synonyms: 2-(1-Phenylvinyl)aniline; benzenamine, 2-(1-phenylethenyl)-
• CAS NO: 64097-92-3
• Molecular Formula: C₁₄H₁₃N
• Molecular Weight: 195.2597
• Mol File: 64097-92-3.mol
• Article Data: 68

Chemical Properties

• Boiling Point: 335.8°C at 760 mmHg
• Flash Point: 166.8°C
• Density: 1.06g/cm³
• Vapor Pressure: 0.000117mmHg at 25°C
• Refractive Index: 1.617
• CAS DataBase Reference: 2-(1-phenylethenyl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(1-phenylethenyl)aniline(64097-92-3)
• EPA Substance Registry System: 2-(1-phenylethenyl)aniline(64097-92-3)

Safety Data

• Hazardous Substances Data: 64097-92-3(Hazardous Substances Data)

Usage

Aromatic amine

has a phenyl group and an ethenyl group attached to the amino group

Uses

Production of dyes, pigments, and optical brighteners; intermediate in the synthesis of various organic compounds; potential applications in pharmaceuticals and organic materials

Precautions

May have toxic and harmful effects if not used properly

Upstream product

• 7664-93-9 sulfuric acid 
• 52744-71-5 1-(2-aminophenyl)-1-phenylethan-1-ol 
• 127-09-3 sodium acetate 
• 108-24-7 acetic anhydride 
• 100-58-3 phenylmagnesium bromide 
• 108-86-1 bromobenzene 
• 551-93-9 2-aminoacetophenone 
• 4545-21-5 acetophenone p-toluenesulfonylhydrazone 
• 615-43-0 2-iodophenylamine 
• 5606-41-7 2-(imino(phenyl)methyl)aniline 
• 536-74-3 phenylacetylene 
• 62-53-3 aniline 
• 2364-50-3 isovaleranilide 
• 1885-29-6 anthranilic acid nitrile 

Downstream Products

• 133901-52-7 N-[2-(1-phenylethenyl)phenyl]acetamide 
• 133363-44-7 N-[2-(1-phenylethenyl)phenyl]formamide 
• 133901-67-4 2,2-Dichloro-N-acetamide 
• 80825-07-6 (+/-)-1,2-dihydro-2-methyl-2,4-diphenylquinoline 
• 20364-46-9 4-phenyl-2-(2'-pyridinyl)quinoline 
• 1039-51-6 2,4-diphenylquinoline 
• 67984-76-3 1-Azido-2-(1-phenyl-vinyl)-benzene 
• 1237588-95-2 N-benzyl-2-(α-phenylstyryl)aniline 
• 1236-89-1 2-(4-methylphenyl)-4-phenylquinoline 
• 1236-90-4 2-(4-chlorophenyl)-4-phenylquinoline 
• 5855-57-2 4-phenyl-2-quinolinone 
• 2584-37-4 1-methyl-4-phenyl-1H-quinolin-2-one 

Relevant articles and documents

Photocatalyzed Intramolecular [2+2] Cycloaddition of N-Alkyl-N-(2-(1-arylvinyl)aryl)cinnamamides

N-Alkyl-N-(2-(1-arylvinyl)aryl)cinnamamides are converted into natural product inspired scaffolds via iridium photocatalyzed intramolecular [2+2] photocycloaddition. The protocol has a broad substrate scope, whilst operating under mild reaction conditions. Tethering four components forming a trisubstituted cyclobutane core builds rapidly high molecular complexity. Our approach allows the design and synthesis of a variety of tetrahydrocyclobuta[c]quinolin-3(1H)-ones, in yields ranging between 20–99 %, and with excellent regio- and diastereoselectivity. Moreover, it was demonstrated that the intramolecular [2+2]-cycloaddition of 1,7-enynes—after fragmentation of the cyclobutane ring—leads to enyne-metathesis-like products.

INDENOACRIDINE COMPOUND AND APPLICATIONS THEREOF

PROBLEM TO BE SOLVED: To provide: a novel indenoacridine compound better in stability against redox and in hole transportability than known conventional compounds; and an organic EL element based on the indenoacridine compound. SOLUTION: An indenoacridine compound represented by general formula (1) or (2) is used. SELECTED DRAWING: None COPYRIGHT: (C)2021,JPOandINPIT

tert-Butyl Hydroperoxide-Initiated Radical Cyclization of 1-(Allyloxy)-2-(1-Arylvinyl)Benzenes with Sulfinic Acids to Access Sulfonated Benzoxepines

A tert-butyl hydroperoxide-initiated radical cyclization of 1-(allyloxy)-2-(1-arylvinyl)benzenes with sulfinic acids for the construction of sulfonated benzoxepines is developed. This reaction involves a radical pathway and offers a straightforward route to the formation of seven-membered ring via sulfonylation/cyclization process. This methodology features mild reaction conditions, a broad substrate scope and good functional group tolerance. (Figure presented.).