6421-52-9Relevant academic research and scientific papers
The Alleged Isolable 1,4,5,6-Tetrachloro-7,7-dimethoxynorbornadiene-2,3-dicarboxylic Anhydride
Jones, David W.,Sunko, Dionis E.,Thornton-Pett, Mark
, p. 721 - 724 (1994)
Addition of dibromomaleic anhydride to tetrachlorocyclopentadienone dimethyl acetal gives the pseudo-lactone 11 (X-ray crystal structure analysis) and not the mixture of endo- and exo-adducts 2 previously claimed; reduction of this product with Zn/HOAc gi
The Role of Norcaradiene Intermediates in the Thermal Rearrangement of Norbornadien-7-one Acetals
Sunko, Dionis E.,Lovric, Zdravko,Vancik, Hrvoj
, p. 1589 - 1590 (2007/10/02)
The bis(methoxycarbonyl)tetrachloronorbornadienone dimethyl acetal (1) rearranges spontaneously to the hemimellitate (2) via the norcaradiene intermediate (6); the corresponding anhydride (5) is stable below 200 deg C because steric strain prevents its conversion into an analogous intermediate (9).
