64244-31-1Relevant academic research and scientific papers
1-Azidoalkylphosphonates - A convenient substrates for the synthesis of N-alkyl α-aminoalkylphosphonates
Gajda,Janik
, p. 493 - 498 (2007/10/03)
Diethyl [1-(alkylamino)alkyl]phosphonates 5 have been efficiently synthesized via a two-step reaction of diethyl 1-azidoalkylphosphonates 1 with triphenylphosphine, followed by in situ transformation of thus formed phosphazenes 2 into imines 4 by means of
Sigmatropic isomerizations in azaallyl systems: XXI. Alkanimidoylphosphonates and their prototropic and phosphorotropic isomers
Onys'ko,Kim,Kiseleva,Sinitsa
, p. 1868 - 1878 (2007/10/03)
Synthetic procedures for alkanimidoylphosphoryl derivatives with α-hydrogen atoms in the N-alkyl radical are developed. Data on the effect of substituents at the carbon and phosphorus atoms on the facility of prototropic transitions in the C=N-C triad are
α-Aminophosphonates. III. Cycloaddition anionique-1,3 des esters α,β-insatures: Preparation et transformations des Δ1-pyrrolines
Dehnel, Andre,Kanabus-Kaminska, Jolanta M.,Lavielle, Gilbert
, p. 310 - 318 (2007/10/02)
The anions of the 2-azaallylphosphonates 1 react with the α,β-unsaturated esters 2 to yield intermediates 4'.These intermediates form the 2-diethoxyphosphonyl-4-ethoxycarbonylpyrrolidines 4 following a protonation while an elimination of the anion of the
