64297-66-1Relevant articles and documents
Mild and efficient synthesis of iodylarenes using Oxone as oxidant
Soldatova, Natalia,Postnikov, Pavel,Troyan, Anna A.,Yoshimura, Akira,Yusubov, Mekhman S.,Zhdankin, Viktor V.
supporting information, p. 4254 - 4256 (2016/08/25)
Mild and efficient method for the preparation of iodylarenes by oxidation of iodoarenes with Oxone in aqueous acetonitrile at room temperature is described. This new procedure allows the preparation of various iodylarenes with electron-donating or electron-withdrawing substituents in the aromatic ring including the previously unknown 1,2-diiodylbenzene.
Syntheses of (diacetoxyiodo)arenes or iodylarenes from iodoarenes, with sodium periodate as the oxidant
Kazmierczak, Pawel,Skulski, Lech,Kraszkiewicz, Lukasz
, p. 881 - 891 (2007/10/03)
Easy, safe, and effective novel methods for preparing either (diacetoxyiodo)-(arenes, ArI(OAc)2, or iodylarenes, ArIO2, from the corresponding iodoarenes, ArI, using sodium periodate as the oxidant are presented in this paper. In order to obtain 2- and 4-iodylbenzoic acids, the respective sodium salts of 2- and 4-iodobenzoic acids should be used as the starting substrates, because mixtures containing the corresponding iodosyl derivatives as the main products along with the intended iodyl compounds are produced from the free parent acids.
