64314-14-3

Upstream product

• 80373-80-4 (R)-4-[(1S,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-1,5-dimethyl-hexyl]-cyclohex-1-enecarboxylic acid methyl ester 
• 80373-74-6 [(1S,3S)-3-((R)-4-Bromomethyl-cyclohex-3-enyl)-1-isobutyl-butoxy]-tert-butyl-diphenyl-silane 
• 80373-71-3 (R)-5-[(1S,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-1,5-dimethyl-hexyl]-2-methyl-cyclohexanone 
• 145353-92-0 methyl (1'R,4R)-4-(2'-formyl-1'-methylethyl)cyclohex-1-ene-1-carboxylate 
• 926-62-5 isobutylmagnesium bromide 
• 17904-27-7 (+)-(4R)-[(S)-1,5-dimethyl-3-oxohexyl]cyclohex-1-enecarboxylic acid methyl ester 
• 930-68-7 cyclohexenone 
• 145353-91-9 methyl (1S,4S,1'S)-(-)-4-(1'-methyl-2'-propenyl)-2-cyclohexenecarboxylate 
• 145414-44-4 methyl (4R,1'S)-(+)-4-(1'-methyl-2'-propenyl)-1-cyclohexencarboxylate 
• 145353-90-8 (1S,4S,1'S)-(-)-4-(1'-methyl-2'-propenyl)-2-cyclohexenylmethanol 
• 145414-43-3 (3aS,7aR)-(+)-2,3,3a,4,5,7a-hexahydrobenzofuran-2-one 
• 145353-87-3 (3S,3aS,7aR)-(+)-methyl-2,3,3a,4,5,7a-hexahydrobenzfuran-2-one 
• 145353-89-5 (1S,6S,1'S)-(+)-2-(1'-methyl-2'-propenyl)-5-cyclohexen-1-ol 
• 68069-67-0 (1S,4S)-(-)-bicyclo<2.2.2>oct-5-en-2-one 

Downstream Products

• 17904-27-7 (+)-(4R)-[(S)-1,5-dimethyl-3-oxohexyl]cyclohex-1-enecarboxylic acid methyl ester 
• 17844-06-3 (R)-4-((R)-3-Hydroxy-1,5-dimethyl-hexyl)-cyclohex-1-enecarboxylic acid 
• 38963-60-9 4-((R)-1,5-Dimethyl-3-oxo-hexyl)-cyclohexanecarboxylic acid methyl ester 
• 86279-09-6 trans-4-<3(S)-hydroxy-1(R),5-dimethylhexyl>cyclohexane-1-carboxylic acid 
• 86279-09-6 cis-4-<3(S)-hydroxy-1(R),5-dimethylhexyl>cyclohexane-1-carboxylic acid 
• 38963-91-6 4-((R)-1,5-Dimethyl-3-oxo-hexyl)-cyclohexanecarboxylic acid 
• 38963-91-6 4-((R)-1,5-Dimethyl-3-oxo-hexyl)-cyclohexanecarboxylic acid 

Relevant academic research and scientific papers

Synthesis of compounds with juvenile hormone activity; XXXI: Stereocontrolled synthesis of (+)-juvabione from a chiral sulfoxide

A stereocontrolled synthesis of (+)-juvabione is described. The key step is a regioselective lithiation of a chiral (E)-butenyl sulfoxide 5 followed by stereoselective 1,4-addition to cyclohex-2-en-1-one. The chiral sulfoxide 5 was prepared by employing a

Synthesis of (+)-Juvabione, a Compound with Juvenile Hormone Activity

(+)-Juvabione 1 was synthesized by employing (1R,4S,6S)-6-hydroxybicyclooctan-2-one 2 as a chiral source. (+)-Juvabione 1 shows juvenile hormone activity, and its racemate has been repeatedly synthesized.Optically active 1 was synthesized by Pawson

SESQUITERPENOIDS RELATED TO JUVABIONE IN ABIES PINSAPO

From the acid fraction of the hexane extract of the wood of Abies pinsapo, four new sesquiterpenoids related to juvabione have been isolated: epitodomatuic acid, cis-dihydroepitodomatuic acid, 4'-dehydroepitodomatuic acid and 3'-dihydroepitodomatuic acid.

A Synthesis of the Juvabiols

Synthetic studies utilizing condensations of α-sulfinyl carbanions, have provided (+)-juvabiol and its analogous diastereoisomers.