64317-34-6

Upstream product

• 56-23-5 tetrachloromethane 
• 771-60-8 2,3,4,5,6-pentafluoroaniline 
• 1801-14-5 1-(N,N-dimethylamine)pentafluorobenzene 
• 58751-08-9 2,3,4,5,6-pentafluoroformanilide 
• 2379-19-3 N,N'-bis(pentafluorophenyl)-hydrazine 

Downstream Products

• 6091-44-7 piperidine hydrochloride 
• 18251-82-6 diisobutylamine hydrochloride 
• 70414-24-3 ethyl pentafluorophenylcarbamate 
• 94055-34-2 ethyl pentafluorophenylchloroformimidate 
• 94055-35-3 C₁₀H₃ClF₉NO 
• 94055-39-7 C₁₃H₆F₁₃NO₂ 
• 94055-40-0 C₁₉F₁₅NO₂ 
• 120672-71-1 2-pentafluoroanilino-4,5,6,7-tetrafluorobenzimidazole 
• 120672-69-7 N¹-phenyl-N²-pentafluorophenylcarbodiimide 
• 76635-16-0 N-Pentafluorophenyl-guanidine 
• 94055-11-5 2-pentafluorophenylimino-1,3-dioxolane 
• 94055-14-8 β-chloroethyl pentafluorophenylcarbamate 

Relevant academic research and scientific papers

REACTIONS OF PENTAFLUOROPHENYLHYDRAZINE AND SOME OF ITS N'-ACYL DERIVATIVES WITH COMPOUNDS CONTAINING A TRICHLOROMETHYL GROUP IN THE PRESENCE OF ALUMUNIUM CHLORIDE

The reactions of pentafluorophenylhydrazine and also of N'-benzoyl-, N'-pentafluorobenzoyl-, and N'-acetylpentafluorophenylhydrazines and decafluorohydrazobenzene with CCl3R (R=Cl, C6H5, C6F5) in the presence of aluminium chloride were investigated.The main products from the reaction of pentafluorophenylhydrazine with the reagents were N-pentafluorophenylhydrazonodichloromethane and N-pentafluorophenylhydrazonoaryl chlorides.Derivatives of 1,3,4-oxadiazol-2-in-5-one were formed in the reactions of N'-acylpentafluorophenylhydrazines with carbon tetrachloride in the pres ence of aluminium chloride.When heated with carbon tetrachloride and aluminium chloride, decafluorohydrazobenzene disproportionates with the formation of decafluoroazobenzene and pentafluoroaniline.

POLYFLUOROARYLCARBONIMIDOYL DICHLORIDES AND CHLORIDES. A NEW METHOD OF OBTAINING SUCH COMPOUNDS FROM POLYFLUOROAROMATIC AMINES AND COMPOUNDS OF THE CCl3R TYPE IN THE PRESENCE OF AlCl3

Reactions of some polyfluorinated amines of the benzene, diphenyl, naphtalene and pyridine series with CCl4 in the presence of AlCl3 have been investigated.A new method is proposed for producing polyfluoroarylcarbonimidoyl dichlorides ArfN=CCl2.The reaction is shown to be sufficiently general and applicable in the series of polychlorinated anilines and low-base anilines of the hydrocarbon series as well.The possibility of involving other compounds of the type CCl3R and other Lewis acids in the reaction has been studied.The factors influencing the course of the reaction and the mechanism of formation of polyfluoroarylcarbonimidoyl dichlorides are discussed.