20455-68-9

Basic information

• Product Name: DIBENZYLAMINE HYDROCHLORIDE
• Synonyms: dibenzylammoniumchloride;n-(phenylmethyl)-benzenemethanaminhydrochloride;DIBENZYLAMINE HCL;DIBENZYLAMINE HYDROCHLORIDE
• CAS NO: 20455-68-9
• Molecular Formula: C₁₄H₁₆N*Cl
• Molecular Weight: 233.74
• EINECS: 243-834-2
• Mol File: 20455-68-9.mol
• Article Data: 17

Chemical Properties

• Melting Point: 260-262°C
• Boiling Point: 300°Cat760mmHg
• Flash Point: 143.3°C
• Appearance: /
• Density: 1.028g/cm³
• Vapor Pressure: 0.00115mmHg at 25°C
• CAS DataBase Reference: DIBENZYLAMINE HYDROCHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: DIBENZYLAMINE HYDROCHLORIDE(20455-68-9)
• EPA Substance Registry System: DIBENZYLAMINE HYDROCHLORIDE(20455-68-9)

Safety Data

• Statements: 36/37/38
• Safety Statements: 26-36/37/39
• Hazardous Substances Data: 20455-68-9(Hazardous Substances Data)

Usage

General Description

Dibenzylamine hydrochloride is a chemical compound composed of dibenzylamine, a secondary amine, and hydrochloric acid. It is commonly used as a reagent in organic synthesis and as a catalyst in the production of various pharmaceuticals and fine chemicals. Dibenzylamine hydrochloride is a white to pale yellow crystalline powder, and it is soluble in water, ethanol, and methanol. It is also used as a corrosion inhibitor, an intermediate in the synthesis of dyes and pigments, and as a stabilizer in the manufacture of polymers. Additionally, dibenzylamine hydrochloride is used in the production of rubber chemicals, textile chemicals, and as a stabilizer in the manufacture of resins and coatings.

InChI:InChI=1/C14H15N.ClH/c1-3-7-13(8-4-1)11-15-12-14-9-5-2-6-10-14;/h1-10,15H,11-12H2;1H

Upstream product

• 100-52-7 benzaldehyde 
• 100-46-9 benzylamine 
• 100-39-0 benzyl bromide 
• 1426958-17-9 N,N-dibenzyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-amine 
• 65-85-0 benzoic acid 
• 1372314-22-1 N,N-dibenzyl-4-cyanophenylamide 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 780-25-6 N-benzylidene benzylamine 
• 421-61-4 (trifluoromethyl)phosphinic acid 
• 75-07-0 acetaldehyde 
• 103-49-1 dibenzylamine 
• 1485-70-7 N-benzylbenzamide 
• 88072-44-0 2,4-dibenzyl-1,5-diphenyl-2,4-diaza-3-thiapentane 
• 102-05-6 N-methyldibenzylamine 

Downstream Products

• 226985-10-0 2-acetylamino-N,N-dibenzyl-4-oxo-4-phenyl-butyramide 
• 100-52-7 benzaldehyde 
• 121527-61-5 penicillin V dibenzylamine salt 
• 6333-30-8 2,6-bis-dibenzylaminomethyl-cyclohexanone; dihydrochloride 
• 35929-26-1 N,N-bis(phenylmethyl)-propionamide 
• 137360-51-1 1-<(dibenzyl)amino>cyclopropanecarbonitrile 
• 110480-76-7 1-{7-[(Dibenzylamino)-methyl]-6-hydroxy-4-methoxy-benzofuran-5-yl}-ethanone 
• 22935-34-8 2-(2-(dibenzylamino)ethyl)cyclobutanone 
• 23825-35-6 N,N-dibenzylbenzamide 
• 50877-01-5 cyclohexanmethylamine hydrochloride 
• 146106-54-9 bis(cyclohexylmethyl)amine hydrochloride 
• 180747-56-2 (N,N)-dibenzyl-3-phenylpropanamide 
• 1408392-42-6 C₂₈H₃₅N₃O 
• 1187336-81-7 C₃₃H₃₃NO₄ 

Relevant articles and documents

A General, Selective, High-Yield N-Demethylation Procedure for Tertiary Amines by Solid Reagents in a Convenient Column Chromatography-like Setup

(Equation presented) A traditional preparative chromatographic column can be used to achieve quantitative N-demethylation of tertiary N-methylamines and alkaloids. The filling is the crucial part and is loaded with different solid reagents in three reaction zones. The parent compound is charged on the column, and the neat N-demethylated secondary amine leaves the column some minutes later.

Lithium compound catalyzed deoxygenative hydroboration of primary, secondary and tertiary amides

A selective and efficient route for the deoxygenative reduction of primary to tertiary amides to corresponding amines has been achieved with pinacolborane (HBpin) using simple and readily accessible 2,6-di-tert-butyl phenolate lithium·THF (1a) as a catalyst. Both experimental and DFT studies provide mechanistic insight. This journal is

Computationally forecasting the effect of dibenzylammonium substituents on pseudorotaxane formation with dibenzo[24]crown-8

The ability to predict the relative stabilities of analogous pseudorotaxanes is essential for the synthetic chemist yet simplified computational forecasting approaches remain scarce. Consequently, ten [2]pseudorotaxanes have been assembled (from a series of para-substituted dibenzylammonium ions and dibenzo[24]crown-8) and their experimentally-determined stabilities correlated with two computational parameters closely related to complexation energy. The strongest relationship was obtained from density functional theory calculation of binding energy (R2 = 0.92) while determination of the maximum surface electrostatic potential on the dibenzylammonium ions (a proxy indicator of complex stability) afforded comparable results (R2 = 0.88) with great reduction in computational expense.