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CAS

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64474-54-0

S-(-)-3-Bromocamphor, also known as bromo-camphor, is a chiral bicyclic ketone compound characterized by its white to off-white crystalline solid form and a distinct camphor-like odor. It is recognized for its asymmetric carbon center, which is pivotal in the creation of enantiomerically pure compounds, a critical aspect in pharmaceuticals and organic synthesis.

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  • 64474-54-0 Structure

  • Basic information

    1. Product Name: S-(-)-3-Bromocamphor
    2. Synonyms: (1S)-ENDO-(-)-3-BROMOCAMPHOR;S-(-)-3-Bromocamphor;(1S)-(-)-3-Bromo Camphor, 98% min;(L)-(-)-3-Bromo camphor;((1S)-ENDO)-(-)-3-BROMOCAMPHOR 98%;L-BROMOCAMPHOR
    3. CAS NO:64474-54-0
    4. Molecular Formula: C10H15BrO
    5. Molecular Weight: 231.13
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 64474-54-0.mol

  • Chemical Properties

    1. Melting Point: 75-77 °C(lit.)
    2. Boiling Point: 274°C
    3. Flash Point: 35.8°C
    4. Appearance: /
    5. Density: 1.365g/cm3
    6. Vapor Pressure: 0.0284mmHg at 25°C
    7. Refractive Index: 1.528
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: S-(-)-3-Bromocamphor(CAS DataBase Reference)
    11. NIST Chemistry Reference: S-(-)-3-Bromocamphor(64474-54-0)
    12. EPA Substance Registry System: S-(-)-3-Bromocamphor(64474-54-0)

  • Safety Data

    1. Hazard Codes: Xi
    2. Statements: 36/37/38
    3. Safety Statements: 26-36
    4. WGK Germany: 3
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 64474-54-0(Hazardous Substances Data)

64474-54-0 Usage

Uses

Used in Pharmaceutical Industry:
S-(-)-3-Bromocamphor is used as a pharmaceutical intermediate for the production of chiral drugs. Its asymmetric carbon center is instrumental in ensuring the purity of enantiomers, which is essential for the efficacy and safety of many medications.
Used in Organic Synthesis:
In the realm of organic synthesis, S-(-)-3-Bromocamphor serves as a valuable chiral auxiliary, facilitating the creation of complex chiral molecules with high selectivity and efficiency.
Used in Agricultural Chemicals:
S-(-)-3-Bromocamphor is also utilized in the production of chiral agricultural chemicals, where the purity of enantiomers can affect the performance and environmental impact of these products.
Used as a Resolving Agent in Analytical Chemistry:
S-(-)-3-Bromocamphor is employed as a resolving agent to separate enantiomers, which is crucial for the analysis and purification of chiral compounds in various chemical and pharmaceutical processes.
Used in Studying Enantioselectivity:
S-(-)-3-Bromocamphor is a valuable tool for researchers studying the enantioselectivity of chemical reactions, providing insights into the mechanisms and outcomes of asymmetric synthesis.
Used in Preparation of Chiral Catalysts:
It is also used in the preparation of chiral catalysts, which are essential for promoting enantioselective reactions, leading to the production of desired enantiomerically pure products.

Check Digit Verification of cas no

The CAS Registry Mumber 64474-54-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,4,4,7 and 4 respectively; the second part has 2 digits, 5 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 64474-54:
(7*6)+(6*4)+(5*4)+(4*7)+(3*4)+(2*5)+(1*4)=140
140 % 10 = 0
So 64474-54-0 is a valid CAS Registry Number.
InChI:InChI=1/C10H15BrO/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6-7H,4-5H2,1-3H3/t6?,7?,10-/m1/s1

64474-54-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name S-(-)-3-Bromocamphor

1.2 Other means of identification

Product number -
Other names 3-bromocamphor

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:64474-54-0 SDS

64474-54-0Relevant articles and documents

New chiral cyclopalladated complexes based on the pinane and bornane imines

Kuchin,Gur'eva,Frolova,Alekseev,Zalevskaya

, p. 745 - 750 (2014/01/23)

2α-Hydroxypinan-3-one imino derivatives react with lithium tetrachloropalladate to form palladacycles, while similar bornane derivative undergo cyclopalladation only when treated with palladium acetate.

REACTIVITY OF 3-BROMOCAMPHOR AND 3-BROMOISOCAMPHANONE UNDER THE CONDITIONS OF THE RITTER REACTION

Koval'skaya, S. S.,Kozlov, N. G.,Zyryanov, V. A.

, p. 722 - 726 (2007/10/02)

The bromination of camphor and isocamphanone yield, respectively, 3-endo- and 3-exo-bromo ketones.Under the conditions of the Ritter reaction 3-bromocamphor does not react with nitriles, while 3-isocamphanone is selectively converted into the corresponding N,N'-diacyl-3-bromo-2,2-gem-diamino-5,5,6-trimethylbicycloheptanes.

Correlation of nuclear magnetic resonance spectra and structure of trans-camphane-2,3-diols

Allen, M. S.,Hutchinson, J. H.,Money, T.

, p. 2707 - 2708 (2007/10/02)

Evidence is provided to demonstrate that a recent correction in the published nmr spectra of trans-camphane-2,3-diols is unjustified

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